Electrically conductive adhesive layer

ABSTRACT

An electrically conductive adhesive layer includes a plurality of particles dispersed between opposing first and second major surfaces of the electrically conductive adhesive layer. The first and second major surfaces are spaced apart a distance D. The particles are agglomerated so as to form a plurality of substantially continuous layers of particles generally extending along orthogonal first and second directions and arranged along a third direction. Each substantially continuous layer of particles has a length L along the first direction from a first to an opposing second edge of the electrically conductive adhesive layer and a width W along the second direction extending from the first to the second major surface. L/D ≥ 100. At least some of the particles are electrically conductive.

BACKGROUND

Magnetic fields can be used to alter a distribution of magneticparticles in a resin.

Electrically conductive adhesives can include electrically conductiveparticles in an adhesive.

SUMMARY

The present disclosure relates generally to films and layers includingparticles. The particles can be oriented and/or aligned and/orpositioned by the methods described herein to provide one or moreimproved properties relative to the case where the particles arerandomly oriented and distributed, according to some embodiments. Atleast some of the particles can be magnetically responsive; at leastsome of the particles can be electrically conductive; and/or at leastsome of the particles can be thermally conductive.

In some aspects of the present disclosure, an electrically conductiveadhesive layer is provided. The electrically conductive adhesive layerincludes a plurality of particles dispersed between opposing first andsecond major surfaces of the electrically conductive adhesive layer. Thefirst and second major surfaces are spaced apart a distance D. Theparticles are agglomerated so as to form a plurality of substantiallycontinuous layers of particles generally extending along orthogonalfirst and second directions and arranged along a third direction. Eachsubstantially continuous layer of particles has a length L along thefirst direction from a first to an opposing second edge of theelectrically conductive adhesive layer and a width W along the seconddirection extending from the first to the second major surface. L/D ≥100. At least some of the particles are electrically conductive.

In some aspects of the present disclosure, an electrically conductiveadhesive layer rolled along a length of the electrically conductiveadhesive layer to form a roll is provided. The electrically conductiveadhesive layer includes a plurality of substantially continuous layersof particles extending along the length and a thickness of theelectrically conductive adhesive layer and arranged along a width of theelectrically conductive adhesive layer. The electrically conductiveadhesive layer has a substantially higher electrical conductivity alongeach of the thickness and the length of the electrically conductiveadhesive layer than the width of the electrically conductive adhesivelayer.

In some aspects of the present disclosure, an electrically conductiveadhesive layer including a plurality of particles dispersed betweenopposing first and second major surfaces of the electrically conductiveadhesive layer is provided. The particles are sufficiently denselypacked so as to form a plurality of substantially continuous layers ofparticles generally extending along orthogonal first and seconddirections. At least one of the first and second directions forms anoblique angle with respect to a thickness direction of the electricallyconductive adhesive layer. At least some of the particles areelectrically conductive.

In some aspects of the present disclosure, an electrically conductiveadhesive layer including pluralities of first and electricallyconductive second particles is provided. The first and second particleshave respective real parts of relative magnetic permeability µʹ₁ andµʹ₂, where for at least one frequency less than about 1 GHz, µʹ₁ / µʹ₂ ≥5. Alternatively, or in addition, the first and second particles canhave different compositions. For at least one cross-section of theelectrically conductive adhesive layer and for each of the first andsecond particles, the particle has alternating higher and lowerdensities. The higher density includes a plurality of the particle.

In some aspects of the present disclosure, an electrically conductiveadhesive layer including a plurality of substantially continuous layersof particles generally extending along orthogonal first and seconddirections and arranged along a third direction is provided. Eachsubstantially continuous layer of particles includes a plurality offirst particles having a first composition and a plurality ofelectrically conductive second particles having a different secondcomposition. Each pair of adjacent substantially continuous layers ofparticles defines a space therebetween. Each of the first and secondparticles has a lower density in the space between, than in each of, thelayers of particles.

In some aspects of the present disclosure, an electrically conductiveadhesive layer including a plurality of alternating first and secondsubstantially continuous layers of respective first and electricallyconductive second particles is provided. The alternating layersgenerally extend along orthogonal first and second directions and arearranged along a third direction. The first and second particles havedifferent compositions.

In some aspects of the present disclosure, an electrically conductiveadhesive layer is provided. The electrically conductive adhesive layerhas first and second major surfaces spaced apart a distance D in athickness direction of the electrically conductive adhesive layer, and alateral length L along a length direction of the layer orthogonal to thethickness direction. L/D ≥ 100. The layer includes a plurality ofparticles dispersed and asymmetrically distributed between the first andsecond major surfaces so that in each of at least a first layercross-section of the layer orthogonal to the length direction and asecond layer cross-section of the layer orthogonal to the thicknessdirection, an ellipse fitted to a cross-section of a two dimensionalautocovariance of an image of the layer cross-section at 10% of acentral peak of the autocovariance has a major axis length L1 and aminor axis length L2, where L1/L2 ≥ 1.2. At least some of the particlesare electrically conductive.

In some aspects of the present disclosure, an electrically conductiveadhesive layer is provided. The electrically conductive adhesive layerhas first and second major surfaces spaced apart a distance D in athickness direction of the electrically conductive adhesive layer, and alateral length L along a length direction of the layer orthogonal to thethickness direction, where L/D ≥ 100. The layer includes a plurality ofparticles dispersed between the first and second major surfaces andregularly arranged so that in each of at least a first layercross-section of the layer orthogonal to the length direction and asecond layer cross-section of the layer orthogonal to the thicknessdirection, a power spectral density of a positive portion of a twodimensional autocovariance of an image of the layer cross-section has apeak corresponding to a pitch of less than about 100 micrometers andcorresponding to the regular arrangement of the particles. At least someof the particles are electrically conductive.

These and other aspects will be apparent from the following detaileddescription. In no event, however, should this brief summary beconstrued to limit the claimable subject matter.

BRIEF DESCRIPTION OF THE DRAWINGS

FIG. 1 is a schematic perspective view of a magnetizable particleaccording to some embodiments of the present disclosure.

FIG. 1A is an enlarged view of region 1A in FIG. 1 .

FIG. 2 is an image of a plurality of magnetic particles arranged with adesired structure due to the application of a magnetic field on asubstrate according to an example of the present disclosure.

FIG. 3 is schematic view of a method of making a film, the method variesa magnetic field by rotating modulation and applies a cure, where underthe influence of the magnetic field, the particles assume a desiredstructure according to some embodiments of the present disclosure.

FIG. 3A is a schematic illustration of a desired structure of aplurality of particles that results from the method of FIG. 3 accordingto some embodiments of the present disclosure.

FIG. 3B is a schematic cross-sectional view of FIG. 3A along the line at3B-3B in FIG. 3A.

FIG. 3C is a schematic illustration of a desired structure ofpluralities of particles that results from the method of FIG. 3according to some embodiments of the present disclosure.

FIG. 3D is a schematic cross-sectional view of FIG. 3C along the line at3D-3D in FIG. 3C.

FIG. 3E is a schematic illustration of another desired structure ofpluralities of particles that results from the method of FIG. 3according to some embodiments of the present disclosure.

FIG. 3F is a schematic cross-sectional view of FIG. 3EC along the lineat 3F-3F in FIG. 3E.

FIG. 4 is a schematic view of an example of a magnet according to someembodiments of the present disclosure.

FIG. 4A is a schematic view showing the magnet of FIG. 4 with themagnetic field having rotating modulating as a result of rotation of themagnet according to some embodiments of the present disclosure.

FIGS. 5A-5C are schematic illustrations of arrangements of a pluralityof particles relative to one another cross-web, down-web and thicknessdirection according to some embodiments of the present disclosure.

FIG. 6 is a schematic cross-section of an exemplary film produced by oneof the methods discussed herein and having multiple layers, where someof the multiple layers contain a plurality of particles according tosome embodiments of the present disclosure.

FIG. 7 is schematic view of a method of forming a film using twomagnetic fields and two cures where a second plurality of particlesassume a second desired structure according to some embodiments of thepresent disclosure.

FIG. 7A is a schematic illustration of a desired structure for thepluralities of particles that results from the two magnetic fields ofthe embodiment method of FIG. 7 .

FIG. 7B is a schematic illustration of a desired structure for the ofparticles that results from the two magnetic fields being pivoted in across-web and down-web directions as indicated by arrows in FIG. 7 .

FIG. 8 is schematic view of a method of forming a film using twomagnetic fields and two cures where some of the plurality of particlesand a second resin are added after the first cure according to someembodiments of the present disclosure.

FIG. 9 is a schematic view of a method of forming a film with a web patharound a single magnet where the single magnet applies a magnetic fieldwith two different orientations relative to the plurality of particlesand the web.

FIG. 9A is a schematic view taken from a first perspective in FIG. 9 .

FIG. 9B is a schematic view taken from a second perspective in FIG. 9 .

FIG. 9C is a schematic illustration of a desired structure for theparticles that results from the two magnetic fields with only the singlemagnet using the arrangement shown in FIG. 9 .

FIG. 10 is a schematic view of a method of forming a film using onemagnetic field that is dithered back and forth about a second axis whilealso undergoing rotating modulation according to some embodiments of thepresent disclosure.

FIG. 10A is a schematic illustration of a desired structure for theparticles that result from the dithering about the second axis androtating modulation of the magnetic field of the embodiment of FIG. 10 .

FIG. 10B is a schematic illustration of a desired structure for theparticles that result from the full rotation about the second axis androtating modulation of the magnetic field of the embodiment of FIG. 10 .

FIG. 11 is a schematic view of a method of forming a film using at leasttwo magnetic fields that are each dithering back and forth while each ofthe magnetic fields also undergoing rotating modulation according tosome embodiments of the present disclosure.

FIG. 11A is a schematic illustration of a desired structure for theplurality of particles that results from the dithering about the secondaxis and rotating modulation of the at least two magnetic fields of theembodiment of FIG. 11 .

FIG. 12 is a schematic view of a method of forming a film where adown-web position that the cure is applied can be changed relative tothe magnetic field showing that different down-web distances experiencea different orientation of the magnetic field according to someembodiments of the present disclosure.

FIG. 12A is a schematic view of the method of FIG. 12 from anotherperspective showing the web can be curved about the magnet such that allcross-web locations of the same down-web location experiencesubstantially the same orientation of the magnetic field according tosome embodiments of the present disclosure.

FIG. 13 is a schematic view of a method of forming a film where adown-web position that the cure is applied is alternated between twolocations (indicated as 0 degrees and 25 degrees) relative to themagnetic field according to some embodiments of the present disclosure.

FIG. 13A is a schematic illustration of a desired structure for theplurality of particles that results from the two alternating curelocations of the method of FIG. 13 .

FIG. 13B is a schematic cross-sectional view of FIG. 13A along line at13B-13B of FIG. 13A.

FIG. 14 is a schematic view of a method of forming a film where aposition of the entire web relative to the surface of the magnet ischanged such that the relative orientation of the magnetic field ischanged relative to the plurality of particles according to someembodiments of the present disclosure.

FIGS. 14A and 14B are schematic illustrations of desired structures forthe plurality of particles that result from combining the method of FIG.14 with the method of FIG. 3 and combining the method of FIG. 14 withthe method of FIG. 12 .

FIG. 14C is a schematic cross-sectional view of FIG. 14A along line14C-14C of FIG. 14A.

FIG. 14D is a schematic cross-sectional view of FIG. 14A along line14D-14D of FIG. 14A.

FIG. 14E is a schematic cross-sectional view of FIG. 14B along line14E-14E of FIG. 14B.

FIG. 15 is a schematic view of a method of forming a film where theangle of the web relative to the magnetic field is changed according tosome embodiments of the present disclosure.

FIG. 15A is a schematic illustration of a desired structure for theplurality of particles that results from the change of the portion ofthe web relative to the magnetic field of the method of FIG. 15 .

FIG. 15B is a schematic cross-sectional view of FIG. 15A along line15B-15B.

FIG. 15C is a schematic cross-sectional view of FIG. 15A through line15C-15C.

FIG. 16 schematically shows further desired structures for the pluralityof particles in films having multiple layers that can be obtained byusing multiple magnetic fields by combining at least the methods ofFIGS. 10-15 , for example.

FIG. 17 is a schematic view of a method of forming a film where a firstmagnetic field is translated in a cross-web direction relative to theweb while undergoing rotating modulation and a second magnetic field isoriented substantially transverse to the first magnetic fields andundergoes rotating modulation according to some embodiments of thepresent disclosure.

FIG. 17A is schematic illustration of a desired structure for theplurality of particles as a result of the two magnetic fields accordingto the method of FIG. 17 .

FIG. 18 is a schematic view of a method of forming a film where one ormore features are imparted in the film prior to, during or afterapplication of the magnetic field and/or cure according to someembodiments of the present disclosure.

FIGS. 19 and 20 schematically show examples of the one or more featuresbeing imparted to the film.

FIG. 21 schematically shows a magnet assembly according to someembodiments where a first portion of the magnet assembly has beenrotated relative to a second portion of the magnetic field such that thepoles of the first and second portions do not align perfectly, thisarrangement for the magnet assembly provides for localizedirregularities in the magnetic field according to some embodiments ofthe present disclosure.

FIG. 22 schematically shows a magnet assembly according to someembodiments that has an irregular diameter with sections having a largerdiameter providing for flux concentrations according to some embodimentsof the present disclosure.

FIGS. 23 and 23A schematically show an embodiment where the substrate ofthe film is varied in thickness in a predetermined manner, the variablethickness is designed to capture and orient the articles as shown inFIG. 23A according to some embodiments of the present disclosure.

FIG. 24 is a schematic side view of a layer or film including aplurality particles according to some embodiments of the presentdisclosure.

FIG. 24A is a schematic cross-sectional view of the layer or film ofFIG. 23 in an orthogonal cross-section.

FIG. 25 is a schematic cross-sectional view of a layer or film includinglayers of particles according to some embodiments of the presentdisclosure.

FIG. 26 is a schematic cross-sectional view of a layer or film includingfirst and second pluralities of particles according to some embodimentsof the present disclosure.

FIG. 27 is a schematic cross-sectional view of a layer or film includingfirst and second pluralities of particles according to some embodimentsof the present disclosure.

FIG. 28 is a schematic top view of a layer or film according to someembodiments of the present disclosure.

FIGS. 29-30 are schematic cross-sectional views of layers or filmsaccording to some embodiments of the present disclosure.

FIG. 31 is a schematic side view of a layer or film including layers ofparticles dispersed in a binder according to some embodiments of thepresent disclosure.

FIG. 32 is a schematic cross-sectional view of a flake.

FIG. 33 is a schematic cross-sectional view of a layer or film includinga plurality of flakes according to some embodiments of the presentdisclosure.

FIG. 33A is a schematic cross-sectional view of a layer or filmincluding pluralities of first and second flakes according to someembodiments of the present disclosure.

FIG. 34 is schematic cross-sectional view of a layer or film pluralitiesof particles according to some embodiments of the present disclosure.

FIGS. 34A-34B are schematic illustration of multimodal sizedistributions of particles according to some embodiments of the presentdisclosure.

FIGS. 35 and 35A are schematic cross-sectional views of a plurality ofmagnets positioned proximate a web according to some embodiments of thepresent disclosure.

FIGS. 36 and 36A are schematic top views of magnets positioned proximatea web according to some embodiments of the present disclosure.

FIGS. 37 and 37A are schematic cross-sectional view of films accordingto some embodiments of the present disclosure.

FIG. 38 is a schematic perspective view or a roll of a layer or filmaccording to some embodiments of the present disclosure.

FIG. 39 is a schematic plot of an autocovariance of an image of a layercross-section according to some embodiments of the present disclosure.

FIGS. 39A-39B are schematic cross-sections of two dimensionalautocovariances of images of layer cross-sections according to someembodiments of the present disclosure.

FIG. 39C is a schematic plot of a positive portion of a two dimensionalautocovariance of an image of a layer cross-section according to someembodiments of the present disclosure.

FIG. 39D is schematic plot of a power spectral density (PSD) of apositive portion of a two dimensional autocovariance of an image of alayer cross-section according to some embodiments of the presentdisclosure.

FIG. 39E is an image of a layer cross-section of a layer orthogonal tothe thickness direction according to some embodiments of the presentdisclosure.

FIG. 39F is a two dimensional autocovariance of the image of the layercross-section of FIG. 39E.

FIG. 39G is a plot showing PSDs of positive portions of a twodimensional autocovariances integrated over a length direction accordingto some embodiments of the present disclosure.

FIG. 40 is a schematic cross-sectional view of a system for wirelesspower transmission according to some embodiments of the presentdisclosure.

FIGS. 41-42 are images showing top and cross-sectional views of amagnetic film;

FIGS. 43 and 43A are images showing top views of a magnetic film atdifferent magnifications.

FIGS. 44 and 44A are images showing cross-sectional views of themagnetic film of FIG. 43 at different magnifications.

FIGS. 45 and 45A are schematic top views of a transmission line.

FIG. 45B is a plot of a power loss versus frequency for magnetic films.

FIG. 45C is a plot of shielding effectiveness versus frequency formagnetic films.

FIG. 45D is a plot of the transmission coefficient versus frequency formagnetic films.

FIGS. 46 and 46A are images of a top view of an adhesive layer atdifferent magnifications.

FIG. 46B is an image of a cross-section of the adhesive layer of FIG. 46.

FIGS. 47 and 47A are plots of signal magnitudes S11 and S21,respectively, versus frequency.

FIGS. 47B and 47C are plots of the real and imaginary parts of theimpedance, respectively, versus frequency.

FIGS. 48, 48A, 48B, 49, 49A, 49B, 50 and 50A are images of top views ofadhesive layers;

FIG. 51 is an image of a cross-section of a thermal interface layer.

FIGS. 52 and 52A are images of top and cross-sectional views,respectively, of another thermal interface layer.

FIG. 53 is an image of a cross-section of a thermal interface layer thatwas not subjected to an applied rotating magnetic field.

FIG. 53A is an image of a cross-section of a thermal interface layerthat was subjected to an applied rotating magnetic field.

FIG. 54 is an image of a cross-section of another thermal interfacelayer that was not subjected to an applied rotating magnetic field.

FIG. 54A is an image of a cross-section of another thermal interfacelayer that was subjected to an applied rotating magnetic field.

FIG. 55 is a plot of thermal conductivity versus total filer volumeloading.

FIG. 56 is a plot of the ratio of the thermal conductivity of samplessubjected to an applied rotating magnetic field to the thermalconductivity of corresponding samples that were not subjected to anapplied rotating magnetic field as a function of the ratio of volume ofmagnetic filler to total filler volume.

DETAILED DESCRIPTION

In the following description, reference is made to the accompanyingdrawings that form a part hereof and in which various embodiments areshown by way of illustration. The drawings are not necessarily to scale.It is to be understood that other embodiments are contemplated and maybe made without departing from the scope or spirit of the presentdescription. The following detailed description, therefore, is not to betaken in a limiting sense.

Films and layers including magnetic particles (particles that are atleast one of magnetizable, magnetically permeable, or magneticallyresponsive) are described. The magnetic particles can be oriented and/oraligned and/or positioned by the methods described herein to provide oneor more improved properties relative to the case where the particles arerandomly oriented and distributed, according to some embodiments. Themagnetic particles may directly or indirectly provide desired propertiesof the film or layer. In some embodiments, a magnetic film includesmagnetic particles which provide a desired magnetic shielding and/ormagnetic absorption, for example. The magnetic film can also includedielectric filler particles to provide a desired response to electricfields. In some embodiments, a film or layer includes magnetic firstparticles and different second particles, where the second particlesprovide, at least in part, desired properties while the first particlesare used, at least in part, to orient and/or align and/or position thesecond particles to enhance the properties provided by the secondparticles. For example, an electrically conductive layer (e.g., anelectrically conductive adhesive layer of an electrically conductivetape) can include magnetic first particles and electrically conductivesecond particles, where the second particles are included to increasethe electrical conductivity in the thickness direction and the firstparticles are used, as least in part, for aligning and/or orientingand/or positioning the second particles which further increases theelectrical conductivity in the thickness direction. As another example,a thermal interface layer (e.g., a layer used to provide or enhancethermal conduction between a hotter object, such as a battery system,and a cooler object, such as a cooling system) can include magneticfirst particles and thermally conductive second particles, where thesecond particles are include to increase the thermal conductance in thethickness direction and the first particles are used, at least in part,for aligning and/or orienting and/or positioning the second particleswhich further increases the thermal conductivity in the thicknessdirection.

A layer of film can be one or more of a magnetic film, a thermalinterface layer, or an electrically conductive adhesive layer. Forexample, a magnetic film can include magnetic particles in an adhesivelayer where the magnetic particles can be electrically conductive and/orwhere additional particles which are electrically conductive areincluded in the adhesive layer, so that the magnetic film is also anelectrically conductive adhesive layer. The magnetic particles and/orthe additional particles can also be thermally conductive so that themagnetic film is also a thermal interface layer. As another example, amagnetic film can include magnetic particles in a layer where themagnetic particles can be thermally conductive and/or where additionalparticles which are thermally conductive are included in the layer sothat the layer is a thermal interface layer. The magnetic particles andthe additional particles, if included, can be electrically insulative sothat the layer is an electrically insulative thermal interface layer.

The methods described herein for orienting and/or aligning and/orpositioning (e.g., magnetic) particles include, in some embodiments,providing the particles in a layer of uncured resin, aligning and/ororienting and/or positioning the particles by applying a magnetic field,and then at least partially curing the resin. It is typically preferredthat there is relative motion between the applied magnetic field and thelayer. For example, moving a sample back and forth in a static magneticfield has been found to provide improved alignment and/or orientationand/or positioning compared to holding the sample fixed in the staticmagnetic field. A similar effect can be achieved by moving the sample byan array of suitably oriented, spaced apart, static magnets. In someembodiments, the layer is passed near a rotating cylinder magnet, forexample, to align and/or orient and/or position the magnetic particlesand optionally other particles included in the layer. Utilizing arotating magnetic field has been found to provide improved alignmentand/or orientation and/or positioning compared to cases where there isno relative motion between the applied magnetic field and the layer. Themethods described herein allow the improved alignment and/or orientationand/or positioning to be achieved throughout the layer in a continuousroll-to-roll process, for example.

As used herein:

A “magnetized” item (e.g., particle) is an item having a magneticmoment, in the absence of an applied magnetic field, of at least 0.001electromagnetic units (emu), in some cases at least 0.005 emu, and yetother cases 0.01 emu, up to an including 0.1 emu, although this is not arequirement. A “magnetizable” item (e.g., particle) is an item capableof being magnetized using an applied magnetic field or an item that isalready magnetized. Useful magnetizable materials include ferromagneticmaterials and ferrimagnetic materials, for example. Typically, appliedmagnetic fields used in practice of the present disclosure have a fieldstrength in the region of the magnetic particles being oriented of atleast about 10 gauss (1 mT), in some cases at least about 100 gauss (10mT), and in yet other cases at least about 1000 gauss (0.1 T), and inyet other cases at least about 10,000 gauss (1.0 T).

A “magnetically permeable” item (e.g., particle) is an item having areal part of relative magnetic permeability µʹ where µʹ-1 issubstantially higher than that of typical weakly paramagnetic materials(typical weakly paramagnetic materials include, for example, air, wood,aluminum and platinum having relative permeabilities of 1.00000037,1.00000043, 1.000022, and 1.000265, respectively). In some cases, amagnetically permeable item has a real part of magnetic permeability µʹthat is at least 1.01 for at least one frequency less than about 1 GHz.In some cases, µʹ is at least 1.02, or at least 1.05, or at least 1.1,or at least 2, or at least 5, or at least 10 for at least one frequencyless than about 1 GHz. Useful magnetically permeable materials includeferromagnetic materials (e.g., iron, nickel, cobalt, or alloys includingat least one of iron, nickel, or cobalt) and ferrimagnetic materials(e.g., ferrite), for example. Useful magnetically permeable particlesalso include superparamagnetic particles (e.g., sufficiently smallnanoparticles made from ferromagnetic or ferrimagnetic materials areknown to exhibit superparamagnetism), for example.

A “magnetically responsive” particle is a particle that responds (e.g.,moves and/or changes orientation when the particle is free to move, orgenerates a force and/or torque when the particle is held in place) toan applied magnetic field to a substantially greater extent than that oftypical weakly paramagnetic particles and typical weakly diamagneticparticles (typical weakly diamagnetic materials include, for example,water, copper, and sapphire having relative of 0.999992, 0.999994, and0.99999976, respectively). In some cases, a magnetically responsiveparticle has a real part of magnetic permeability µʹ such that |µʹ-1| isat least 0.01 for at least one frequency less than about 1 GHz. In somecases, |µʹ-1| is at least 0.02, or at least 0.05, or at least 0.1, or atleast 1, or at least 2, or at least 5, or at least 10 for at least onefrequency less than about 1 GHz. Useful magnetically responsiveparticles include particles containing ferromagnetic materials orferrimagnetic materials, and superparamagnetic particles.

A “magnetic particle” is a particle that is at least one ofmagnetizable, magnetically permeable, or magnetically responsive.

A “thermally conductive” item is an item having a thermal conductivityof greater than 0.5 W/mK along at least one direction. In some cases, athermally conductive item (e.g., a particle) has a thermal conductivityof at least 1 W/mK, or at least 5 W/mK, or at least 10 W/mK, or at least20 W/mK, or at least 30 W/mK (e.g., along at least one direction). Insome cases, the thermal conductivity is at least 1 W/mK, or at least 5W/mK, or at least 10 W/mK, or at least 20 W/mK, or at least 30 W/mKalong at least two orthogonal directions (e.g., in the plane of athermally conductive plate or along each of three mutually orthogonaldirection in a particle extending in each of the three directions (e.g.,a substantially spherical particle)).

An “electrically conductive” item is an item having an electricalresistivity of no more than 200 µΩ cm (evaluated at low frequencies(e.g., about 1 kHz or less) or evaluated statically (direct current))along at least one direction. An electrically conductive particle canhave an electrical resistivity of no more than 20 µΩ cm, or no more than10 µΩ cm, or no more than 5 µΩ cm, for example. Magnetic and electricproperties are determined at 20° C., unless indicated differently.

An “electrically insulative” item is an item having an electricalresistivity of at least 100 Ω m (evaluated at low frequencies (e.g.,about 1 kHz or less) or evaluated statically (direct current)) alongeach direction. An electrically conductive particle can have anelectrical resistivity of at least 1 kΩ m, or at least 1 MΩ m, or atleast 1 GΩ m, for example.

A “dielectric particle” is a particle having a real part of dielectricconstant greater than 1.8 for at least one frequency less than about 1GHz. In some cases, the dielectric constant is greater than 2, 3, 5, or10 for at least one frequency less than about 1 GHz. A dielectricparticle is typically an electrically insulative particle. Thedielectric constant may also be referred to as the relativepermittivity.

The term “orientation”, “orient”, “orienting”, or “oriented” as itrefers to the particles of the present disclosure can refer to anon-random disposition of at least a majority of the particles relativeto a substrate, which is sometimes referred to as a backing herein, orrelative to a major surface of the layer including the particles, orrelative to a thickness direction of the layer. For example, a majorityof the particles can have a major planar surface disposed at an angle ofat least 70 degrees relative to a first major surface of the substrateafter application of the magnetic field (or of no more than 30 degreesrelative to a thickness direction of the substrate or a layer includingthe particles). These terms can also refer to major axes and dimensionsof the particles themselves. For example, the particle maximum length,width and thickness are a function of a shape of the particle, and theshape may or may not be uniform. The present disclosure is in no waylimited to any particular particle shape, dimensions, type, etc., andmany exemplary magnetic particles useful with the present disclosure aredescribed in greater detail below. However, with some shapes, the“length”, “width” and “thickness” give rise to major faces and minorside faces. Regardless of an exact shape, any particle can have localCartesian axes (e.g., principle axes) as shown in FIG. 1 u (length whichcan be the longest dimension along a principle axes), v (width), and w(thickness which can be the smallest dimension along a principle axes)defined. With these conventions, the particle w-axis is parallel withthe maximum thickness, the particle u-axis is parallel with the maximumlength, and the particle v-axis is parallel with the maximum width ofthe particle. As a point of reference, the particle axes can identifiedfor each particle as a standalone object independent of the backingconstruction; each magnetic particle (along with the particle’s local(uvw) coordinate system) can be manipulated by a magnetic field to causethe particle to achieve a desired orientation relative to a global (xyz)coordinate system, where the x-axis is down-web (length), the y-axis iscross-web (width), and the z-axis is normal to the xy-plane (thickness)Refer to FIG. 3 and additional FIG. 2-23B. A “z-axis rotationorientation” of the particle can be defined by the particle’s angularrotation about a z-axis passing through the particle and normal to thebacking or parallel to the thickness direction. The orientation effectedby the magnetic field(s) of the present disclosure can entailapplication of the magnetic field to alter or otherwise change a spatialarrangement of at least a majority of the plurality of the magneticparticles relative to the substrate and/or on a particle level to adesired range of rotational orientations about the particle in one ormore of the z-axis, the y-axis and/or the x-axis to a range ofrotational orientations about the particle axes.

The term “position”, “positioning”, “position”, or “position” as itrefers to particles of the present disclosure can refer to a non-randomdisposition of at least a majority of the particles relative to oneanother. For example, a majority of the particles may be spaced adesired distance apart in at least one axis after application of themagnetic field.

The term “alignment”, “aligning”, “aligned”, or “align” as it refers tothe particles of the present disclosure can refer to a non-randompositioning of at least a majority of the particles. Specifically,having “alignment” can position a majority of the particles such that amajority of the particles have major surfaces that are substantiallyparallel with one another substantially orthogonal to one another,and/or are oriented at a desired angle with respect to one another.

The term “desired structure” means a structure formed from a pluralityof particles where at least a majority of the plurality of particleshave one or more of an orientation, position, and/or alignment relativeto one another and/or the substrate that has been affected byapplication of the magnetic field(s).

The term “vitrification”, “vitrified”, “vitrifying”, or “vitrify” as itrefers to the resin mixture containing the magnetic particles and/orother particles means increasing the viscosity of the resin mixture soas to enable at least a majority of the particles maintain their desiredstructure after application of the magnetic field(s). Vitrification maybe only partially accomplished to a sufficient amount so as to enable atleast a majority of the magnetic particles maintain their desiredstructure after application of the magnetic field(s). Vitrification mayoccur via polymerization (e.g. radiation curable or thermally curableresin systems), solidification through removal of thermal energy (e.g.solidification of a polymer melt), or evaporation of a solvent from theresin mixture. The terms “Cure”, “Cure 1” and “Cure 2” as used in thisdocument are all vitrification processes.

Magnetic particles are described herein by way of example and can havevarious configurations. For example, the magnetic particles can beconstructed of various materials including but not limited to ceramics,metal alloy powder, metal alloys, glass particles coated to bemagnetizable, or composites, for example. Similarly, the magneticparticles can be substantially entirely constructed of magnetizablematerial, can have magnetizable portions disposed therein (e.g., ferroustraces), or can have magnetizable portions disposed as layers on one ormore surfaces thereof (e.g., one or more surfaces can be coated with amagnetizable material) according to some examples. The magneticparticles, or other particles, can be shaped according to some examples,such as shown in the example of FIG. 1 . According to some examples, theparticles can include flakes, crush grains, agglomerates, substantiallyspherical particles (e.g., particles that are nominally spherical orparticles that can reasonably be considered to be approximatelyspherical), substantially ellipsoidal particles (e.g., particles thatare nominally ellipsoidal or particles that can reasonably be consideredto be approximately ellipsoidal), and/or substantially spheroidalparticles (e.g., particles that are nominally spheroidal or particlesthat can reasonably be considered approximately spheroidal), forexample. The particles can be used in loose form (e.g., free-flowing orin a slurry) prior to cure and can be incorporated into various articlesincluding the films or layers discussed herein.

Referring now to FIGS. 1 and 1A, an exemplary magnetic particle 100 isdisclosed. The magnetic particle 100 can have a shaped body 110 that hasbeen coated with a magnetizable and/or magnetically permeable and/ormagnetically responsive material 120. According to some examples, thebody 110 need not be shaped but can be random. Furthermore, the body 110can be formed of a magnetic material (magnetizable and/or magneticallypermeable material) and need not be coated. The magnetic material 120can include magnetic particles 125 (e.g., iron) retained in a bindermatrix 130 (also referred to simply as “binder”) as further shown inFIG. 1A. If shaped, as it need not be in many embodiments, but as shownin the embodiment of FIG. 1 , the body 110 can have two opposed majorsurfaces 160, 162 connected to each other by four minor side surfaces140 a, 140 b, 140 c and 140 d. Magnetic particles of the type shown canbe moveable to align with magnetic field lines of force as will bediscussed subsequently to form desired structures.

The magnetic material 120 can be a unitary magnetic material, or it caninclude magnetic particles in a binder matrix. Suitable binders can bevitreous or organic, for example, as described for the binder matrix 130hereinbelow. The binder matrix can be, for example selected from thosevitreous and organic binders. The body 110 can include ferrous materialsor non-ferrous material(s), for example.

If the magnetic material includes a layer coated on the particle 100 asshown in the embodiment of FIG. 1 , this can be accomplished by anysuitable method such as, for example, dip coating, spraying, painting,physical vapor deposition, and powder coating. Individual magneticparticles can have magnetic layers (layers that include magneticmaterials) with different degrees of coverage and/or locations ofcoverage. The magnetic material can be essentially free of (i.e.,containing less than 5 weight percent of, in yet other cases containingless than 1 weight percent of) materials used in the shaped body 110.The magnetic layer can consist essentially of magnetic materials(e.g., >99 to 100 percent by weight of vapor coated metals and alloysthereof), or it can contain magnetic particles retained in a bindermatrix. The binder matrix of the magnetic layer, if present, can beinorganic (e.g., vitreous) or organic resin based, and is typicallyformed from a respective binder precursor.

Magnetic particles according to the present disclosure can be prepared,for example, by applying a magnetic layer or precursor thereof to thebody 110. Magnetic layers can be provided by physical vapor depositionas discussed hereinbelow. Magnetic layer precursors can be provided as adispersion or slurry in a liquid vehicle. The dispersion or slurryvehicle and can be made by simple mixing of its components (e.g.,magnetic particles, optional binder precursor, and liquid vehicle), forexample. Exemplary liquid vehicles include water, alcohols (e.g.,methanol, ethanol, propanol, butanol, ethylene glycol monomethyl ether),ethers (e.g., glyme, diglyme), and combinations thereof. The dispersionor slurry can contain additional components such as, for example,dispersant, surfactant, mold release agent, colorant, defoamer, andrheology modifier. Typically, after coating onto the ceramic bodies themagnetic layer precursor is dried to remove most or all of the liquidvehicle, although this is not a requirement. If a curable binderprecursor is used, then a curing step (e.g., heating and/or exposure toactinic radiation) generally follows to provide the magnetic layer.

Vitreous binder can be produced from a precursor composition including amixture or combination of one or more raw materials that when heated toa high temperature melt and/or fuse to form a vitreous binder matrix.Further disclosure of appropriate vitreous binders that can be used withthe article can be found in PCT Publication Nos. WO 2018/080703, WO2018/080756, WO 2018/080704, WO 2018/080705, WO 2018/080765, WO2018/080784, WO 2018/080755, and WO 2018/080799, for example.

In some embodiments, the magnetic layer can be deposited using a vapordeposition technique such as, for example, physical vapor deposition(PVD) including magnetron sputtering. PVD metallization of variousmetals, metal oxides and metallic alloys is disclosed in, for example,U.S. Pat. Nos. 4,612,242 (Vesley) and 7,727,931 (Brey et al.). Magneticlayers can typically be prepared in this general manner.

As discussed previously, the body of the magnetic particle can be shaped(e.g., precisely-shaped) or random (e.g., flake, crushed). Exemplaryshapes include squares, spheres, rectangles, pyramids (e.g., 3-, 4-, 5-,or 6-sided pyramids), truncated pyramids (e.g., 3-, 4-, 5-, or 6-sidedtruncated pyramids), cones, truncated cones, rods (e.g., cylindrical,vermiform), prisms (e.g., 3-, 4-, 5-, or 6-sided prisms), spheres,spheroids, and ellipsoids. A flake can have a thickness small (e.g.,smaller by a factor of at least 4, or at least 8) compared to a largestlateral dimension of the flake and may have an irregular edge shape, forexample.

Exemplary magnetic materials that can be suitable for use in magneticparticles can include: iron; cobalt; nickel; various alloys of nickeland iron marketed as Permalloy in various grades; various alloys ofiron, nickel and cobalt marketed as Fernico, Kovar, FerNiCo I, orFerNiCo II; various alloys of iron, aluminum, nickel, cobalt, andsometimes also copper and/or titanium marketed as Alnico in variousgrades; alloys of iron, silicon, and aluminum (typically about 85:9:6 byweight) marketed as Sendust alloy; Heusler alloys (e.g., Cu₂MnSn);manganese bismuthide (also known as Bismanol); rare earth magnetizablematerials such as gadolinium, dysprosium, holmium, europium oxide,alloys of neodymium, iron and boron (e.g., Nd₂Fe₁₄B), and alloys ofsamarium and cobalt (e.g., SmCo₅); MnSb; MnOFe₂O₃; Y₃Fe₅O₁₂; CrO₂; MnAs;and ferrites such as magnetite; zinc ferrite; nickel ferrite; cobaltferrite, magnesium ferrite, manganese zinc ferrite, barium ferrite, andstrontium ferrite; yttrium iron garnet; and combinations of theforegoing such as nickel zinc ferrite, cobalt nickel zinc ferrite, andmagnesium manganese zinc ferrite. In some embodiments, the magneticmaterial includes at least one metal selected from iron, nickel, andcobalt, an alloy of two or more such metals, or an alloy of at one suchmetal with at least one element selected from phosphorus and manganese.In some embodiments, the magnetic material is an alloy (e.g., Alnicoalloy) containing 8 to 12 weight percent (wt. %) aluminum, 15 to 26 wt.% nickel, 5 to 24 wt. % cobalt, up to 6 wt. % copper, up to 1 wt. %titanium, where the balance of material to add up to 100 wt. % is iron.In some embodiments, the magnetic particles are carbonyl iron particles.Carbonyl iron can be prepared by the chemical decomposition of purifiediron pentacarbonyl. In some embodiments, the magnetic particles includeiron. In some embodiments, the magnetic particles include carbon andiron. In some embodiments, the magnetic particles include nickel.

The magnetic particles can have a major dimension of any size relativeto a thickness of the layer they are a part of but can be much smallerthan the thickness of the layer in some instances. For example, they canbe 1 to 2000 times smaller in some embodiments, in yet other embodiments100 to 2000 times smaller, and in yet other embodiments 500 to 2000times smaller, although other sizes can also be used.

Suitable magnetic particles include particles formed from any of themagnetic materials described elsewhere, optionally coated with anothermaterial, and particles formed from a nonmagnetic material and coatedwith a magnetic material. For example, suitable magnetic particlesinclude nickel coated graphite, nickel coated glass, nickel coatedpolymer (e.g., nickel coated polymethylmethacrylate (PMMA) particles),and silver coated nickel.

In some embodiments, a film or layer includes first and secondparticles. The first particles can be magnetic particles. The secondparticles can be one or more of dielectric particles, electricallyconductive particles, or thermally conductive particles. Suitableelectrically conductive particles include silver coated nickel, silvercoated glass, and metallic particles such as copper or silver particles.Suitable dielectric particles include one or more of copper oxide (e.g.,heat treated Cu(II) oxide), carbon, or BaTiO₃. Suitable thermallyconductive particles include alumina particles (e.g., alpha aluminapowder, substantially spherical alumina particles, or polyhedralalumina), boron nitride particles (e.g., boron nitride flakes orsubstantially spherical boron nitride particles), metallic particles,and metal oxides, carbides, hydrates or nitrides.

In some embodiments, a film or layer includes first and secondparticles. In some embodiments, the first particles include carbon andiron. In some embodiments, the first particles include at least one ofiron or nickel. In some embodiments, the second particles include copperoxide. In some embodiments, the second particles include at least one ofalumina or boron nitride. In some embodiments, the second particlesinclude at least one of silver and copper. In some embodiments, thefirst particles include one or more of iron or nickel, and the secondparticles include one or more of aluminum, magnesium, silicon, copper,or zinc. An advantage of such embodiments is that a high thermalconductivity for a given filler loading, or a low filler loading for agiven thermal conductivity, can be achieved with cost effective fillers.The aluminum, magnesium, silicon, copper, or zinc may or may not be intheir elemental form. For example, an aluminum particle containsaluminum in its elemental form, while an alumina particle containsaluminum not in its elemental form. The second particles can be orinclude aluminum, alumina (aluminum oxide), aluminum trihdrate (ATH),silica (silicon oxide), magnesium oxide, silicon carbide, copper, zincoxide, aluminum nitride, or silver, for example. In some embodiments,the second particles have an isotropic thermal conductivity. In otherembodiments, the second particles have an anisotropic thermalconductivity (e.g., boron nitride flakes or graphite flakes typicallyhave a substantially higher in-plane conductivity than out of planethermal conductivity).

FIG. 2 is a photograph of a film 200 with a plurality of magneticparticles 202 that have been organized into a desired structure with amajority of the magnetic particles exhibiting a non-random positioningalong lines of force due to the application of a magnetic field. Asshown in FIG. 2 , at least a majority of the magnetic particles 202 arealigned and spaced into a desired structure 204 having distinctive rows.In FIG. 2 , the plurality of magnetic particles 202 are Sendustparticles. Other magnetic particles described herein could be used inplace of the Sendust particles. The Sendust particles account forsubstantially 20% of the film by weight percentage and are applied as aslurry onto a substrate. The Sendust particles are initially dispersedin a resin in a random manner.

The type of resin chosen can depend on the desired application. Forexample, it may be desired for the cured resin to be apressure-sensitive adhesive (PSA) in some applications (e.g.,electrically conductive tape), while in other applications, it isdesired that the cured resin be free of tackiness, and in still otherapplications some degree of tack is desired but less tack than that of atypical PSA. Suitable resins include acrylics, silicones, urethanes, andepoxies, for example. The resin can include suitable curing agents(e.g., amines such as tetraethylenepentamine in epoxy systems), and/orrheology modifiers such as diluents, for example.

Types of resin families that can be used include but are not limited to:a combination of a first and a second polymerizable component selectedfrom (meth)acrylate monomers and (meth)acrylate oligomers, and mixturesthereof. As used herein, “monomer” or “oligomer” is any substance thatcan be converted into a polymer. The term “(meth)acrylate” refers toboth acrylate and methacrylate compounds. In some cases, thepolymerizable composition can include a (meth)acrylated urethaneoligomer, (meth)acrylated epoxy oligomer, (meth)acrylated polyesteroligomer, a (meth)acrylated phenolic oligomer, a (meth)acrylated acrylicoligomer, and mixtures thereof. The polymerizable resin optionallyfurther includes at least one crosslinker having three or more(meth)acrylate groups. The polymerizable composition may optionallyinclude a (e.g. monofunctional) reactive diluent. The polymerizableresin can be a radiation curable polymeric resin, such as a UV curableresin. Radiation (e.g. UV) curable compositions generally include atleast one photoinitiator. The photoinitiator or combination ofphotinitiators can be used at a concentration of about 0.1 to about 10weight percent. More preferably, the photoinitiator or combinationthereof is used at a concentration of about 0.2 to about 3 weightpercent. In general, the photoinitiator(s) are at least partiallysoluble (e.g. at the processing temperature of the resin) andsubstantially colorless after being polymerized. The photoinitiator maybe (e.g. yellow) colored, provided that the photoinitiator is renderedsubstantially colorless after exposure to the UV light source. Types ofresin families can also include but are not limited to: a polymerizableresin including of high molecular weight polymers, epoxides and/orsiloxanes.

The resin can be at least partially cured after the Sendust particlesare organized into the desired structure by the applied magnetic field.Due to the high aspect ratio of the Sendust flakes, there can beinitially little to no transmission through the slurry prior toorganization by the magnetic field. Once the magnetic field is applied,the Sendust particles are organized into the desired structure, with thefield lines orienting the Sendust particles (flakes) upward and aligningthem relative to one another.

FIG. 3 shows a method 300 for making a layer or film 302 according tosome embodiments of the present disclosure. FIG. 3A shows a desiredstructure 304 of the plurality of particles 306 that results from themagnetic field of the method of FIG. 3 . Particles 306 can be magneticparticles, or particles 306 can be particles that are ordered and/oraligned and/or positioned due to the presence of other particles whichare magnetic particles. It should be noted that in FIG. 3A, and in thesubsequently shown and described methods and the desired structures ofFIG. 4-23A, that the desired structures, methods and films are shown ona larger scale (high level) such that individual particles of theplurality of particles are not specifically shown. Thus, each row orlayer (shown as a line) of the desired structures will include some ofthe plurality of the particles. It should be recognized that the desiredstructures include the plurality of particles, which may be spaced fromone another even when grouped in rows or layers as shown in FIG. 2 . Itshould be further recognized that for the disclosed methods a majority(or more) of the plurality of particles may exhibit the desiredstructure and the desired structures shown herein are often shown in ahighly schematic manner that does not show some degree of randomnessthat can occur in the orientation, alignment and/or positioning of atleast some (e.g., less than a majority) of the particles. Thisrandomness is shown in some areas of the film of FIG. 2 .

The method 300 is operable to provide the plurality of particles 306with the desired structure 304 within the layer or film 302 as shown inFIG. 3A. FIG. 3B shows a cross-section of FIG. 3A showing the desiredstructure 304 from another perspective.

In some embodiments, a layer or film includes pluralities of first andsecond particles. In some embodiments, the first particles are magneticparticles and the second particles are electrically conductive and/orthermally conductive. The first particles may be magnetic while thesecond particles may be magnetic or nonmagnetic.

FIG. 3C shows a structure 304 a of the plurality of first particles 306and a plurality of second particles 306 a in a layer or film 302 a thatcan result from the magnetic field of the method of FIG. 3 . FIG. 3Dshows a cross-section of FIG. 3C showing the desired structure 304 afrom another perspective. The first particles 306 are arranged in layers320 and the second particles 306 a are arranged in layers 320 a.

FIG. 3E shows a structure 304 b of the plurality of first particles 306and a plurality of second particles 306 b in a layer or film 302 b thatcan result from the magnetic field of the method of FIG. 3 . FIG. 3Fshows a cross-section of FIG. 3E showing the structure 304 b fromanother perspective. The first particles 306 are arranged in layers 320and the second particles 306 b are arranged in layers 320 b which may besubstantially coincident with layers 320 (e.g., the first and secondparticles can be mixed in a same layer).

Whether the first and second particles form coincident or alternatinglayers typically depend of the magnetic properties of the particles andin some cases on the size of the particles. In the embodiment of FIGS.3C-3D, first particles 306 can be magnetic particles and the secondparticles 306 a can be nonmagnetic or substantially less magnetic thanthe first particles 306. For example, the first and second particles canhave respective first and second respective real parts of relativemagnetic permeability µʹ₁ and µʹ₂ where for at least one frequency lessthan about 1 GHz, µʹ₁ / µʹ₂ ≥ 5. The relative magnetic permeability of aparticle may be be taken to be the relative magnetic permeability of thebulk material making up the particle, or in the case of a compositeparticle, the relative magnetic permeability may be taken to be theeffective relative permeability as determined by effective mediumtheories such as the magnetic Clausius-Mossotti or Maxwell-Garnettmodels. The second particles 306 a can have a size comparable to orlarger than the first particles 306, for example. If the secondparticles 306 a were much smaller than the first particles 306, thesecond particles 306 a could be substantially randomly distributedbetween layers of the first particles 306. In some embodiments, anaverage spacing between substantially continuous layers of the firstparticles 306 is less than an average longest dimension of the secondparticles 306 a (see, e.g., FIG. 52A). In the embodiment of FIGS. 3E-3F,the first and second particles 306 and 306 b can both be magneticparticles (e.g., each having a relative magnetic permeability of atleast 2 for at least one frequency less than about 1 GHz). Particleshaving similar magnetic properties tend to be arranged in the samelayers.

In some embodiments, for at least one cross-section of the layer or filmand for each of the first and second particles, the particle hasalternating higher and lower densities, the higher density including aplurality of the particle. A particle has alternating higher and lowerdensities when a density of the particle alternates along at least onedirection defining higher and lower density regions of the particle. Thehigher density of the particle includes a plurality of the particle wheneach higher density region includes a plurality of the particle. Inother words, in some embodiments, for at least one cross-section of thelayer or film, the first particles are distributed in alternating higherand lower density regions where each higher density region of the firstparticles includes a plurality of the first particles, and the secondparticles are distributed in alternating higher and lower densityregions where each higher density region of the second particlesincludes a plurality of the second particles. In some embodiments, inthe at least one cross-section of the layer or film, the higherdensities of the first particle alternate with the higher densities ofthe second particle (see FIGS. 3C-3D). In some embodiments, in the atleast one cross-section of the layer or film, the first and secondparticles have substantially coincident alternating higher and lowerdensities (see FIGS. 3E-3F). For example, the higher and lower densitiesmay occur within a same layer and may be coincident to within thethickness of the layer.

The plurality of particles 306 can have a construction similar to themagnetic particles illustrated or described elsewhere herein. Accordingto some embodiments and now referencing FIG. 3 , the particles can bedispersed in a resin to form a first mixture 308. The resin can have acomposition the same as the examples provided in reference to FIG. 2 ,for example. The first mixture 308 can be positioned on a web 310(including a substrate 312). The plurality of particles 306, or total ofthe first particles 306 and second particles 306 a or 306 b, can beanywhere from 0.01% to 90% percent by weight of the first mixture 308.The particular chemical composition and thickness of the substrate 312can depend on the desired attributes of the particular product that isbeing constructed. That is, balancing the needs for strength,temperature resistance, surface energy, adherence to the coated layer,among others. The thickness of the substrate 312 is typically at leastabout 0.025 millimeters (mm) and more typically at least about 0.125 mm.Further, the substrate 312 generally has a thickness of no more thanabout 0.5 mm.

Useful substrate materials include, for example, styrene-acrylonitrile,cellulose acetate butyrate, cellulose acetate propionate, cellulosetriacetate, polyether sulfone, polymethyl methacrylate, polyurethane,polyester, polycarbonate, polyvinyl chloride, polystyrene, polyethylenenaphthalate, copolymers or blends based on naphthalene dicarboxylicacids, polyolefin-based material such as cast or orientated films ofpolyethylene, polypropylene, and polycyclo-olefins, polyimides, andglass. Optionally, the substrate material can contain mixtures orcombinations of these materials. In an embodiment, the substrate may bemultilayered or may contain a dispersed component suspended or dispersedin a continuous phase. In some embodiments, after the resin is cured,the substrate is removed. For example, the substrate can be a releaseliner or a carrier layer that is removed from the layer before the layeris used in an application.

Further examples of substrates include polyethylene terephthalate (PET)and polycarbonate. Examples of useful PET films include photogradepolyethylene terephthalate and available from DuPont Films ofWilmington, Del. under the trade designation “Melinex 618”.

Optionally, a second substrate (which can be similar or dissimilar incomposition and thickness as the first substrate 312) may be laminated(e.g., bonded (permanently or releasably) using an adhesive) to the film302 to protect the coated layer or to provide a desired physicalproperty to the resulting film, for example.

The first mixture 308 can be applied up-web of a magnet 314 (permanentor electromagnet). A magnet, such as magnet 314, can be an individualmagnet or an assembly of magnets that can act like a single magnet, forexample. The magnet 314 can be placed in close proximity (within a fewfeet) of the web 310 containing the first mixture 308 of the pluralityof particles 306 (and optionally particles 306 a and/or 306 b) andresin. A Cartesian coordinate system is provided in FIGS. 3 and 3B toaid in understanding the positioning of the web 310 relative to themagnet 314 and in understanding the desired structure 304 of FIG. 3A.According to the embodiment shown, the Cartesian coordinate systemprovided can have an axis (x-axis) oriented in the down-web/up-webdirection. The (y-axis) substantially aligns with a cross-web directionof the web 310 and with an axis of rotation AR of the magnet 314. The(z-axis) substantially aligns normal to both of the x-axis and y-axis.

As shown in the example of FIG. 3 , the magnet 314 is rotated about theaxis of rotation AR relative to the web 310. The rotational speed of themagnet can be between 100 to 10,000 rpm or more. The web 310 cantranslate relative to the magnet 314 as indicated by arrow 316. FIGS. 4and 4A show construction of the magnet 314 in further detail. FIG. 4shows the magnet 314 can include two poles N and S that are each shapedas hemispheres and are disposed to either side of the axis of rotationAR. FIG. 4A shows a magnetic field 318 that is generated by the magnet314 and rotating modulation of the magnetic field 318 that results fromrotation of the magnet 314 about the axis of rotation AR (FIGS. 3 and 4). The film 302 and other details of the method 300 of FIG. 3 are notshown in FIG. 4A. The resolved line of force that would be exerted onthe magnetic particles in the coated layer is indicated by arrows A inFIG. 4A.

Further examples of magnetic field configurations and apparatuses forgenerating them are described in U.S. Patent Appl. Pub. Nos.2008/0289262 A1 (Gao) and U.S. Pat. Nos. 2,370,636 (Carlton), 2,857,879(Johnson), 3,625,666 (James), 4,008,055 (Phaal), 5,181,939 (Neff), andBritish Pat. No. GB 1 477 767 (Edenville Engineering Works Limited),which are each hereby incorporated herein by reference to the extentthat it does not contradict the present disclosure.

Returning now to FIG. 3 , according to the example embodiment, themagnet 314 is positioned to extend across a full cross-web extend of theweb 310 in the y-axis direction of the Cartesian coordinate systemprovided. However, in some embodiments the magnet 314 may not extend thefull cross-web width as shown in FIG. 3 . FIG. 3 additionally shows themethod 300 applies at least one cure to the layer or film 302, indicatedas Cure 1 in FIG. 3 . The Cure 1 is applied in close proximity (within afew inches up-web or down-web) of the magnet 314. The Cure 1 can beapplied by any known technique such as, but not limited to, applicationof ultraviolet light, application of electron beam, application orremoval of thermal energy (e.g., applying heating or cooling), forexample. As shown in FIG. 4A, as the magnetic field 318 is undergoingrotating modulation, the application of Cure 1 should be applied to thelayer or film 302 at a particular time and location where the lines offorce and resolved force is oriented in a desired manner in order thatthe plurality of particles are in the desired structure 304, 304 a, or304 b (FIGS. 3A-3F). The Cure 1 can be a full cure (i.e. fullpolymerization of the resin can occur) or can be a partial cure withsufficient polymerization such that a majority of the particles are inthe desired structure. With a full cure no second cure (indicated asCure 2) would be needed in the method of FIG. 3 . FIG. 3 shows themethod 300 having a partial cure (Cure 1) and a second cure (Cure 2) ata down-web location to complete full polymerization.

Thus, the method 300 of FIG. 3 can include positioning the first mixture308 on the substrate 312. The first mixture 308 can include theplurality of particles 306 and optionally particles 306 a and/or 306 bdispersed in the first resin. The method 300 can include assembling theplurality of particles into the desired structure by rotating modulationof at least the magnetic field 318 relative to the plurality ofparticles. The method 300 can further include vitrifying (such as by theCure 1 and/or the Cure 2 discussed above) to increase a viscosity of thefirst resin while the particles are in the desired structure.

FIGS. 3A-3F shows the desired structure 304, 304 a, and 304 b at a highlevel and in a highly schematic manner. As shown in FIG. 3A, forexample, the substrate 312 (FIG. 3 ) can be removed. However, in otherembodiments the substrate 312 can be retained. As discussed previously,individual ones of the plurality of particles are not shown in FIGS.3A-3F. FIG. 3A shows a configuration for the layer or film 302 with thedesired structure 304 similar to that of the magnetic film 200 of FIG. 2. The desired structures 304, 304 a, and 304 b are structures where theparticles are arranged in spaced rows or layers 320, 320 a or 320 bextending generally in the down-web direction.

The embodiments of FIGS. 3 and 3A-3F are described with application ofthe first mixture 308 as a single layer on the substrate. However,applications of multiple layers using the same mixture or differentmixture compositions are also contemplated, and indeed, are furtherdescribed and illustrated in this disclosure. As one illustrativeexample, a magnetic film can include two layers where one of the layersprovides a high magnetic permeability in the thickness direction and ina first in-plane direction and where the other of the two layersprovides a high magnetic permeability in the thickness direction and ina second in-plane direction not parallel to the first in-planedirection. In other embodiments, a single layer is preferred. In anyembodiment describing desired structures in different layers, a singlelayer can be provided having the desired structure shown in any of thedifferent layers.

FIGS. 5A-5C show further potential orientations, positions andalignments of exemplary ones of the plurality of particles describedherein. FIG. 5A shows a particular orientation for particles 402 and 404with minor surfaces arranged in the z and x directions of the Cartesiancoordinate system (same orientation system as utilized in FIG. 3-4A) andthe major surfaces oriented in the y-direction. Such orientation ispurely exemplary in nature and is used for ease of reference anddescription. In the multilayer orientation of FIG. 5A the particles 402and 404 are stacked and spaced from one another. In some embodiments,the particles 402 and 404 can be configured to be attracted or repelledfrom one another as indicated by arrow A.

FIG. 5B shows particles 406 and 408 that are spaced from one another ina cross-web direction. In some embodiments, the particles 406 and 408can be configured to be attracted or repelled from one another asindicated by arrow A. FIG. 5C shows particles 410 and 412 that arespaced from one another in a cross-web direction. In some embodiments,the particles 410 and 412 can be configured to be attracted or repelledfrom one another as indicated by arrow A. Multiple arrangements of theplurality of particles (e.g., arrangements of FIG. 5A, FIG. 5B and/orFIG. 5B) are contemplated, and indeed, are disclosed herein.

FIG. 6 shows one possible configuration for a film 500 having multiplelayers. The film 500 can have a substrate 502 as previously describedand a first layer 504. The first layer 504 can include a first mixture506 of a first resin 508 and a first plurality of particles 510. Thefirst layer 504 can be coupled to the substrate 502 either directly orindirectly. The relative size and spacing of the first plurality ofparticles 510 has been exaggerated for illustration purposes and viewerunderstanding in FIG. 6 . As shown in FIG. 6 , the first plurality ofparticles 510 have a first desired structure 511.

In FIG. 6 , a second layer 512 can be coupled either directly orindirectly (via a second substrate for example) to the first layer 504.The second layer 512 can include a second mixture 514 of a second resin516 and a second plurality of particles 518. The relative size andspacing of the second plurality of particles 518 has been exaggeratedfor illustration purposes and viewer understanding in FIG. 6 . As shownin FIG. 6 , the second plurality of particles 518 have a second desiredstructure 519. The second desired structure 519 can differ from or besubstantially similar to the first desired structure 511.

The particles 510 and/or 518 may be magnetic particles, or other typesof particles (e.g., electrically and/or thermally conductive) that areordered by the presence of other particles (not shown in FIG. 6 ) whichare magnetic as generally described for FIGS. 3C-3F, for example.

As shown in FIG. 6 , the first plurality of particles 510 can have atleast one of a shared first orientation or first common alignmentdirection relative to the substrate 502 and the second plurality ofparticles 518 can have at least one of a shared second orientation orsecond common alignment direction relative to the substrate 502. In FIG.6 , the shared first orientation or first common alignment directiondiffers from the shared second orientation or second common alignmentdirection.

Optionally, further layers can be added to the film 500 including layershaving particles with further desired structures. The embodiment of FIG.6 shows a further layer 520 that can be configured to provide a smoothsurface to the film 500 along an opposing side of the film from thesubstrate 502. In other cases, the further layer 520 can provide adesired texturing or other physical attributes if desired.

FIG. 7 shows another method 600 of forming a film 602 with at least twolayers. Unless otherwise further indicated for the remainder of thisdisclosure, the construct and arrangement of the magnet(s), resin(s),particles, substrate(s), etc. can be substantially similar to or thesame as those previously described herein. Thus, for example, eachmagnet(s), unless otherwise indicated, undergoes rotation similar tothat of the magnet 314 of FIG. 3-4A. Thus, the magnetic field(s)generated by such magnet(s) are subject to rotating oscillation.

The method 600 can include positioning the first mixture 608 (indicatedin “Apply Mixtures”) on a substrate 612. The first mixture 608 caninclude the plurality of (e.g., magnetic) particles 606 (see FIGS. 7Aand 7B) dispersed in a first resin 607 (FIGS. 7A and 7B). The method 600can include assembling the first plurality of particles 606 into thedesired structure 604A or 604B (again reference FIGS. 7A and 7B) byrotating modulation of a first magnetic field 618 relative to theplurality of particles 606. The method 300 can further includevitrifying to increase a viscosity of the first resin (indicated as“Cure 1”) while the plurality of particles 606 are in the desiredstructure 604A or 604B.

FIGS. 7A and 7B shows the desired structures 604A and 604B that canresult from the method 600. These desired structures result fromorienting the first magnet 614 and a second magnet 620 both cross-weband down-web relative to the film 602. This orientation of the first andsecond magnets 614 and 620 changes the magnetic fields 618 and 622 asapplied to the first plurality of particles 606 and a second pluralityof particles 624.

The orientation of the first magnet 614 can be changed relative to thefilm 602 as indicated by arrows A1 about axis AA1 in FIG. 7 . Similarly,the orientation of the second magnet 620 can be changed relative to thefilm 602 as indicated by arrow A2 about axis AA2. By orienting the firstmagnet 614 and/or the second magnet 620 as desired relative to oneanother and to the film, different overall desired structures can beobtained including the first desired structures 604A and 604B (viaorientation/re-orientation of the first magnet 614). FIGS. 7A and 7Bfurther show second desired structures 626A and 626B for the secondplurality of particles 624 that result from orientation/re-orientationof the second magnet 620. The second desired structures 626A combinedwith the first desired structures 604A provide the overall desiredstructures shown in FIG. 7A. The second desired structure 626B combinedwith the first desired structures 604B provide the overall desiredstructure shown in FIG. 7B. To reiterate, the overall desired structuresof FIGS. 7A and 7B can differ due to the different orientation of thefirst magnet 614 and the second magnet 620.

It should be noted that FIGS. 7A and 7B provide just two examples ofpossible desired structures and further desired structures havingdifferent shapes due to the orientation of the first and second magnetsrelative to the film are also contemplated although not specificallyshown. It should also be further noted that although FIGS. 7A and 7Bappear to show the first desired structures 604A or 604B in a same layeras the second desired structures 626A or 626B, this is a result of theviewing orientation of FIGS. 7A and 7B, and that the first desiredstructures 604A or 604B would actually be positioned in a differentlayer of the film 602 than the second desired structures 626A or 626B.

Because the method 600 of FIG. 7 forms the film 602 with multiplelayers, the method 600 can include forming a second mixture 628(indicated in “Apply Mixtures”) that includes the second plurality ofparticles 624 (FIGS. 7A and 7B) dispersed in a second resin 630. Themethod 600 can position the second mixture 628 on one or more of thesubstrate, a second substrate or the first mixture. The method 600 canassemble the second plurality of particles 624 into the second desiredstructure 626A or 626B further by rotating modulation of the secondmagnetic field 622 relative to the second plurality of particles 624.The method can increase a viscosity of the second resin 630 (indicatedas Cure 2) while the second plurality of particles 624 are rows in thesecond desired structure 626A or 626B.

In some embodiments, the second mixture 628 and the first mixture 608have one of a different composition or substantially a same composition.If the composition of the first mixture 608 and the second mixture 628are substantially the same composition, the second mixture 628 can bepositioned according to the method 700 of FIG. 8 , after increasing theviscosity of the first resin 607 while the first plurality of particlesis in the first desired structure 604A or 604B.

FIG. 8 shows a further method 700 of forming the film 602 with at leasttwo layers. The method 700 differs from the method 600 of FIG. 7 in thatthe second mixture 628 can be applied to the web at the labeled (“AddLayer(s)”) after the Cure 1 such that the second resin 630 (FIGS. 7A and7B) is not cured with the first resin 607 (FIGS. 7A and 7B).

FIGS. 9, 9A and 9B show a method 800 of forming a film 802 havingmultiple layers that can be applied before Cure 1 or before Cure 1 andthen again before Cure 2. The method 800 can provide for the firstdesired structures 604A or 604B and the second desired structures 626Aor 626B, for example, as previously described due to the orientation ofthe magnet 804 relative to the film 802. The method 800 of FIGS. 9, 9Aand 9B differs from FIGS. 7-8 in that a single magnet 804 can beutilized. The distance between the magnet axis of rotation and the webat Cure 1 may be different than that between the axis of rotation andthe web at Cure 2. The single magnet 804 generates a first appliedmagnetic field 808 having rotating modulation on the film 802 in theregion of Cure 1 as seen by view A of FIGS. 9 and 9A and produces asecond applied magnetic field 810 having rotating modulation (thatdiffers from the first applied magnetic field 808 due at least toorientation) in the region of Cure 2 as seen by view B of FIG. 9B. Inthis manner, the method 800 can use a single magnet to produce desiredstructures 812 and 814 such as those of FIG. 9C in multiple layers ofthe film 802.

FIG. 10 show a method 900 of forming a film 902 that can be the same asthe method 300 save that the magnet 904 can be moved in a ditheringmanner as indicated by arrows O1 and O2 back-and-forth about axis AA3.This dithering movement would be in addition to the rotation of themagnet 904 about the axis of rotation AR as previously described. Thus,a magnetic field 906 generated by the magnet 904 would have bothrotating modulation and dithering relative to the film 902.

FIG. 10A shows a desired structure 908 for the plurality of particles910, which can be magnetic particles or particles ordered due to thepresence of magnetic particles) in the film 902 that results fromapplication of the magnetic field 906. The desired structure 908 has asinusoidal pattern in a down-web direction due to the dithering movementof the magnetic field 906.

FIG. 10B shows another desired structure 912 for the plurality ofparticles 910 in the film 902 according to another embodiment, whererather than dithering back-and-forth in an arc of less than 360 degreesas shown in FIG. 10 , the magnet 904 would be fully rotated 360 degreescontinuously around the axis AA3 to produce the repeating ring likestructures shown in FIG. 10B.

FIG. 11 show a method 1000 of forming a film 1002 that is identical tothe method 900 of FIG. 10 save that the method utilizes a plurality ofmagnets 1004 and 1006 and the film 1002 has a plurality of layers. FIG.11A shows the film 1002 with the desired structures 1008 and 1010 fortwo of the layers. The desired structure 1008 has a first plurality of(e.g., magnetic) particles 1012. The desired structure 1010 has a secondplurality of (e.g., magnetic) particles 1014. The first plurality ofparticles 1012 have an orientation that differs from that of the secondplurality of particles 1014.

FIG. 12 shows a method 1100 of forming a film 1102 where the location ofthe at least partial cure can be shifted up-web or down-web due to amagnet 1106. This shift in the cure can be to a location where the linesof force from a magnetic field 1104 undergoing rotating modulation dueto rotating of the magnet 1106 are at different angles relative to amajor surface 1108 of the film 1102. It should be noted that in theembodiment of FIG. 12 , the magnet 1106 has been reoriented relative topreviously shown and described magnets. The magnet 1106 has an axis ofrotation AR that generally extends up-web and down-web and is alignedwith the x-direction of the Cartesian coordinate system (this system hasbeen maintained throughout the FIGS.). Angles of the lines of forceexperienced by the film 1102 are indicated as measured from an anglesubstantially orthogonal to the major surface 1108 such that an angle of0 degrees is substantially orthogonal to the major surface, an angle of25 degrees is substantially 25 degrees from orthogonal and an angle of45 degrees is substantially 45 degrees from orthogonal, etc.

FIG. 12A shows the method 1100 of FIG. 12 but at an angle orthogonal tothe view of FIG. 12 . FIG. 12A further shows that the film 1102 can becurved or otherwise shaped in the cross-web direction by a roller, aircurrents, tenting, web tensioning or another technique. This shaping ofthe magnetic film 1102 in the cross-web direction can cause the majorsurface 1108 of the magnetic film 1102 to have a curvature thatgenerally corresponds with and matches a curvature of the magnet 1106.This shaping of the film 1102 allows the major surface 1108 toexperience substantially a same relative angle for the lines of force ofthe magnetic field 1104 in the cross-web direction as indicated byarrows A. Put another way, because of the curvature of the film 1102substantially matching that of the curvature of the outer surface of themagnet 1106, each of the arrows A has substantially a same anglerelative to the major surface 1108. Thus, the magnetic particlesexperience substantially a same relative angle for the magnetic field1104 even if they are located in different cross-web locations.

FIG. 13 shows an example utilizing the method 1100 previously describedin FIG. 12 where the location of the cure in the down-web direction isaltered relative to the magnet 1106 such that the lines of force fromthe magnetic field 1104 undergoing rotating modulation due to rotatingof the magnet 1106 are at angles of substantially 0 degrees measuredfrom orthogonal to the major surface 1108 and substantially 25 degreesmeasured from orthogonal to the major surface 1108.

FIG. 13A shows a desired structure 1110 that results for the film 1102from the method of FIG. 13 . FIG. 13B shows the desired structure 1110in cross-section along line 13B - 13B of FIG. 13A. In some embodiments,as generally described for FIGS. 3A-3F, first and second particles areincluded where the first particles are disposed in layers as indicatedin FIG. 13B and the second particles are in the same layers, or indifferent layers between the layers shown in FIG. 13B.

FIG. 14 shows a method 1200 where the relative position of a layer orfilm 1202 is changed (as indicated by arrow A) relative to a magnet 1204having a magnetic field 1205. More specifically, the film 1202 can bemoved between a relatively closer position 1206 and a relatively furtherposition 1208 from the magnet 1204 and the magnetic field 1205 such thata distance between a major surface 1214 of the layer or film 1202 andthe axis of rotation AR of the magnet 1204 is changed. The tracks of theparticles tend to be more closely spaced when the layer or film 1202 isin the relatively closer position 1206 and the tracks of the pluralityof magnetic particles tend to be more widely spaced when the layer orfilm 1202 is in the relatively further position 1208. It should be notedwith FIGS. 14 and 15 (discussed subsequently) that the magnet 1204, 1304is oriented substantially cross-web such as previously shown in FIG. 3 ,and therefore, is not oriented in the manner of FIGS. 12-13 . However,it should be noted that in other embodiments, the magnet 1204, 1304could be oriented relative to the film 1202, 1302 as shown in FIGS.12-13 and the method 1200, 1300 utilized to obtain different desiredstructures than are shown in FIGS. 14A, 14B and 15A.

FIGS. 14A and 14B show a desired structure 1210 for the plurality ofparticles 1212. FIGS. 14C-14E show the desired structure 1210 fromvarious cross-sections of FIGS. 14A and 14B. FIG. 14A an undulatingtrack of the plurality of particles 1212 in the down-web (x-direction)formed by combining the method of FIG. 14 and the method of FIG. 3 ,where the method of FIG. 3 tends to from down-web tracks and the methodof FIG. 14 tends to vary the spacing of these tracks. FIG. 14B is formedby combining the method of FIG. 14 and the method of FIG. 12 , where themethod of FIG. 12 tends to from cross-web tracks and the method of FIG.14 tends to vary the spacing of these tracks. In some embodiments, asgenerally described for FIGS. 3A-3F, first and second particles areincluded where the first particles are disposed in layers as indicatedin any one of FIGS. 14B-14E and the second particles are in the samelayers, or in different layers between the layers shown in thesefigures.

FIG. 15 shows a method 1300 where the relative position of only a firstportion 1303 of a layer or film 1302 is changed (as indicated by arrowA) relative to a magnet 1304 having a magnetic field 1305. Morespecifically, the first portion 1303 of the film 1302 can be moved(e.g., tilted) between a relatively closer position 1306 and arelatively further position 1308 from the magnet 1304 and the magneticfield 1305. A second end 1307 of the film 1302 can remain insubstantially a same position or only a slightly altered positionrelative to the magnet 1304 and the magnetic field 1305.

FIG. 15A shows a desired structure 1310 that results from the back andforth change in position of the first portion 1303 of the film 1302 fromthe position of 1306 and the position of 1308. FIGS. 15B and 15C arecross-sections of the desired structure 1310 from FIG. 15A. As shown inFIG. 15A, the change to position 1308 and back to position 1306 resultsin the regions 1312 where the particles are tilted cross-web. In someembodiments, as generally described for FIGS. 3A-3F, first and secondparticles are included where the first particles are disposed in layersas indicated in FIGS. 15B or 15C and the second particles are in thesame layers, or in different layers between the layers shown in FIGS.15B or 15C.

FIG. 16 shows examples where various of the methods 900-1300 arecombined to form multilayer films 1402, 1404 and 1406. Indeed, it shouldbe noted that any of the methods disclosed herein can be combined ormodified such as to form multilayer films having a plurality ofparticles organized in various desired structures.

FIG. 17 is a method 1500 according to another embodiment for making afilm 1502 that has a first and a second plurality of (e.g., magnetic)particles 1504, 1505 organized in an overall desired structure 1506 asshown in FIG. 17A. The method 1500 can utilized at least two magnets1508 and 1510. The first magnet 1508 can rotate about an axis ofrotation AR and can have a first magnetic field 1512 with rotatingmodulation. The second magnet 1510 can rotate about an axis of rotationAR and can have a second magnetic field 1514 with rotating modulation.Additionally, the first magnet 1508 can translate back-and-forth in thecross-web (y-axis) direction as indicated by arrows T1 and T2.

FIG. 17A shows the overall desired structure 1506 for the multilayerfilm 1502 that results from the method 1500 with the first plurality ofparticles 1504 positioned, oriented and/or aligned by the first magneticfield 1512 into a first desired structure 1516 and the second pluralityof particles 1505 positioned, oriented and/or aligned by the secondmagnetic field 1514 into a second desired structure 1518. As shown inFIG. 17A, the rows of the first plurality of particles 1504 of the firstdesired structure 1516 are oriented transverse to the rows of the secondplurality of particles 1505 of the second desired structure 1518.

FIG. 18 shows a method 1600 where features 1604 and/or 1606 can beimparted to a layer or film 1602 before, during or after at least apartial cure of the at least a first mixture containing an opticallyclear resin and a plurality of magnetic particles. FIG. 18 shows themethod 1600 performing a first partial cure (“Cure 1”) adjacent a firstmagnet 1608 and applying a second full cure (“Cure 2”) down-web from thefirst magnet 1608. The features that can be imparted to the film 1602 orcan be fabricated prior so as to be inherent in the initial web of thelayer or film 1602 prior to application of the method 1600. The featurescan include, but are not limited to, temporarily curving the layer orfilm 1602 in a cross-web direction (previously shown in FIGS. 12 and12A), curving/distorting the layer or film 1602 in the up-web/down-webdirection, imparting further, particles, substrates, and/or layers tothe film (previously described), adding texture to the substrate (shownin FIG. 19 ), adding a texture to the layer containing the plurality ofmagnetic particles (shown in FIG. 20 ), using a profiled die or anothertool to impart thickness variation into the mixture/layer, providing fora discontinuous layer containing the plurality of particles, providingfor localized irregularities in the magnetic field, providing for fluxconcentrations in the magnetic field, increasing or decreasing the fieldstrength (the magnetic force) applied by the magnet, and/or providingthe substrate with a variable thickness.

FIG. 19 shows the method 1600 where features are imparted to thesubstrate by an apparatus 1610 prior to, during, or after the at leastpartial cure (“Cure 1” of FIG. 18 ). These features can includetexturing of the substrate either cross-web, down-web or both such thatthe position and angle of the substrate of the substrate relative to theaxis of rotation of the magnet can vary from one region (region 1612) toanother region. This texturing of the substrate can alter the layer 1614containing the plurality of particles such that the plurality ofparticles in one region can have a different positioning, orientation oralignment relative to those in other regions. FIG. 20 shows the method1600 where features are imparted directly to the layer 1614 by theapparatus 1610 rather than the substrate. Texturing the layer 1614 canvary the thickness of the layer 1614 containing the plurality ofparticles either cross-web, down-web or both such that the plurality ofparticles in one region can have a different positioning, orientation oralignment relative to those in other regions.

FIG. 21 shows a magnet 1702 that is a composite assembly to formlocalized irregularities in its magnetic field 1704. More particularly,the magnet 1702 has a first portion 1706 with a first magnetic field1708 and a second portion 1710 with a second magnetic field 1712. Thefirst portion 1706 is rotated about axis A slightly such that the pole Nof the first portion 1706 does not align directly with the pole N of thesecond portion 1710. Thus, the first magnetic field 1708 differs inorientation from the second magnetic field 1712, such shift inorientation is called a localized irregularity in the presentdisclosure.

FIG. 22 shows a magnet 1802 with a magnetic field 1804 having fluxconcentrations 1806 due to projections 1808 along the surface of themagnet 1802. Such projections can be part of the magnet 1802 or can beferrous pieces that are separate from the magnet 1802. Furtherinformation regarding flux concentrations can be found in PCTPublication No. WO 2018/136269.

FIGS. 23 and 23A show a film 1902 with a substrate 1904 fabricated witha variable thickness. The substrate 1904 can have alternating peaks 1906and valleys 1908. The valleys 1908 can be configured to receive aplurality of (e.g., magnetic) particles 1910 therein as shown in FIG.23A. The optically clear resin is not shown in FIG. 23A. The peaks 1906can be configured to assist the plurality of particles 1910 to achieve adesired orientation by guiding the plurality of particles 1910 into theorientation shown in FIG. 23A and by supporting the plurality ofparticles 1910 along the sides thereof. The valleys 1908 can beconfigured to assist the plurality of particles 1910 to be positionedwith the desired orientation as well as relative spacing as shown inFIG. 23A.

FIG. 24 is a schematic side view of a layer or film 2080 including aplurality particles 30, according to some embodiments. FIG. 24A is aschematic cross-sectional view of the layer or film 2080 in anorthogonal cross-section. The layer or film 2080 includes the particles30 dispersed between opposing first (10) and second (20) major surfacesof the layer or film 2080 which are spaced apart by a distance D. Theparticles 30 are agglomerated so as to form a plurality of substantiallycontinuous layers 41 of particles generally extending along orthogonalfirst (e.g., x) and second (e.g., z or z′ indicated in FIG. 25 )directions and arranged along a third direction (e.g., y-direction). Alayer of particles can be described as substantially continuous when, ina plan view facing a major surface of the layer, the particles covergreater than 50 percent of an area of the layer (in some cases, theparticles cover at least 60% or at least 70% of the area) and aredistributed throughout the layer such that there are no large (comparedto the D50 particle size, where the D50 particle size is the median sizefor a volume distribution and is sometimes denoted Dv50) open regionsthat do not contain particles (e.g., no open regions having orthogonallength and width directions each larger than 4 D50, or 2 D50, or D50).Each substantially continuous layer 41 of particles 30 has a length Lalong the first direction (x-direction) from a first (37) to an opposingsecond (38) edge of the layer or film 2080 and a width W along thesecond direction (z-direction or z′-direction) extending from the first(10) to the second (20) major surface. In some embodiments, L/D ≥ 100,or L/D ≥ 300, or L/D ≥ 1000. In some embodiments, W/D is at least 0.5,or 0.6, or 0.7, or 0.9. In some such embodiments, W/D is no more than1.5 (W/D can be greater than 1 as schematically illustrated in FIG. 25), or no more than 1.2, or no more than 1. In some embodiments, W/D isabout 1 (e.g., the layer of particles can extend between the opposingmajor surfaces). In some embodiments, D is less than about 1 mm, or lessthan about 500 micrometers, or less than about 200 micrometers. In someembodiments, D is in a range of about 30 micrometers to about 500micrometers, or about 50 micrometers to about 200 micrometers. In someembodiments, the particles 30 are magnetic particles. In someembodiments, the particles 30 are nonmagnetic particles and otherparticles (not shown in FIGS. 24 and 24A) are magnetic particles. Theparticles 30 can be thermally conductive and/or electrically conductive,for example.

In some embodiments, each substantially continuous layer of particleshas a thickness T along a fourth direction (e.g., y-direction ory′-direction (see FIG. 25 )) orthogonal to the first and seconddirections. The thickness T can be an average thickness of the layer. Insome embodiments, D/T ≥ 100. In some embodiments, the third (e.g.,y-direction) and fourth directions are substantially parallel (e.g.,within 30 degrees, or 20 degrees, or 10 degrees, or 5 degrees ofparallel). In some embodiments, the substantially continuous layers 41of particles 30 have an average thickness T and an average separation S,where S ≥ T. In some embodiments, at least some of the substantiallycontinuous layers 41 of particles 30 are substantially parallel to oneanother.

In some embodiments, the layers 41 of particles are tilted relative to athickness direction of the layer or film. FIG. 25 is a schematiccross-sectional view of a layer or film 2180 generally corresponding tolayer or film 2080 except that the layers 41 of particles 30 extendgenerally along the x- and z′-directions. In some embodiments, a layeror film 2180 includes a plurality of particles 30 dispersed betweenopposing first and second major surfaces of the layer or film 2180. Theparticles 30 are sufficiently densely packed so as to form a pluralityof substantially continuous layers 41 of particles generally extendingalong orthogonal first (e.g., x) and second (e.g., z′) directions, atleast one of the first and second directions forming an oblique anglewith respect to a thickness direction (z-direction) of the layer or film2180. For example, the second direction z′ forms an oblique angle φ withthe thickness direction z in the illustrated embodiment. In someembodiments, at least some of the particles are thermally conductive. Insome embodiments, at least some of the particles are electricallyconductive.

In some embodiments, the layer or film (e.g., 2080 or 2180) is amagnetic film and the plurality of particles 30 is a plurality ofmagnetically permeable particles. In some embodiments, the layer or film(e.g., 2080 or 2180) is an electrically conductive adhesive layer andthe plurality of particles 30 is a plurality of electrically conductiveparticles. In some embodiments, the layer or film (e.g., 2080 or 2180)is a thermal interface layer and the plurality of particles 30 is aplurality of thermally conductive particles.

In some embodiments, the layer or film includes different first andsecond particles. FIGS. 26-27 are schematic cross-sectional views oflayers or films 2280 and 2380, respectively, that includes first andsecond particles 30 and 32. Layers or films 2280 and 2380 correspond tolayer or film 2080, for example, except for including both first andsecond particles.

In some embodiments, a layer or film 2180 or 2280 includes pluralitiesof first (30) and second (32) particles having respective real parts ofrelative magnetic permeability µʹ₁ and µʹ₂, where for at least onefrequency less than about 1 GHz, µʹ₁ / µʹ₂ ≥ 5. Alternatively, oradditionally, the first and second particles can have differentcompositions. In some embodiments, for at least one cross-section of thefilm or layer and for each of the first and second particles, theparticle has alternating higher and lower densities, where the higherdensity includes a plurality of the particle. The first particle 30 hasalternating higher (40) and lower (50) densities, and the secondparticle 32 has alternating higher (42) and lower (52) densities. Insome embodiments, in the at least one cross-section of the layer or film2280, the first and second particles have substantially coincident(e.g., coincident or coincident to within a thickness of the layer ofparticles or to within half a thickness of the layer) alternating higherand lower densities (e.g., in FIG. 26 , higher densities 40 and 42 aresubstantially coincident, and lower densities 50 and 52 aresubstantially coincident). In some embodiments, in the at least onecross-section (e.g., y-z cross-section) of the layer or film 2380, thehigher densities 40 of the first particle 30 alternate with the higherdensities 42 of the second particle 32. Similarly, in some embodiments,in the at least one cross-section of the layer or film 2380, the lowerdensities 50 of the first particle 30 alternate with the lower densities52 of the second particle 32. In some embodiments, the at least onecross-section includes a cross-section (e.g., y-z cross-section)parallel to a thickness direction of the layer or film. In someembodiments, the at least one cross-section includes a cross-section(e.g., x-y cross-section) orthogonal to a thickness direction of thelayer or film (see, e.g., FIGS. 3C and 3E).

In some embodiments, the layer or film (e.g., 2280 or 2380) is amagnetic film, the plurality of particles 30 is a plurality of firstmagnetically responsive particles, and the plurality of particles 32 isa plurality of second magnetically responsive particles. In someembodiments, the layer or film (e.g., 2280 or 2380) is an electricallyconductive adhesive layer, the plurality of particles 30 is a pluralityof magnetically responsive particles, and the plurality of particles 32is a plurality of electrically conductive particles. In someembodiments, the layer or film 2080 is a thermal interface layer, theplurality of particles 30 is a plurality of magnetically responsiveparticles, and the plurality of particles 32 is a plurality of thermallyconductive particles.

In some embodiments, the first particles 30 and/or the second particles32 include at least one of substantially spherical particles,substantially spheroidal particles, or substantially ellipsoidalparticles. In some embodiments, the first particles are or includeflakes, as described further elsewhere herein, and the second particlesare or include at least one of substantially spherical particles,substantially spheroidal particles, or substantially ellipsoidalparticles.

In some embodiments, the layer or film (e.g., 2080, 2180, 2280, 2380, orlayers or films described elsewhere herein) has at least one propertythat has different values in different directions. For example, propertyα schematically illustrated in FIGS. 24 and 24A has values α₁, α₂, andα₃ along the x-, z- and y-directions, respectively. In some embodiments,the property α is the real part of the relative magnetic permeability ofthe layer or film (e.g., when the layer or film is a magnetic film). Insome embodiments, the property α is the thermal conductivity of thelayer or film (e.g., when the layer or film is a thermal interfacelayer). In some embodiments, the property α is the electricalconductivity of the layer or film (e.g., when the layer or film is anelectrically conductive adhesive layer). In some embodiments, α₂ > α₃.In some embodiments, α₁ > α₃. In some embodiments, α₂ > α₁.

In some embodiments, a layer or film (e.g., 2080, 2180, 2280, 2380, orlayers or films described elsewhere herein) has first and second thermalconductivities (e.g., corresponding to α₂ and α₃ of FIGS. 24 and 24A)along substantially mutually orthogonal respective first (e.g., z) andsecond (e.g., y) directions, where the first and second directions aresubstantially parallel to at least one cross-section (e.g., y-zcross-section and/or a cross-section where the particles havealternating higher and lower densities). In some embodiments, the firstthermal conductivity is greater than the second thermal conductivity byat least a factor of 2. In some embodiments, a thermal interface layer,or other layer or film described herein, has a thermal conductivity inthe thickness direction of the layer of at least 2 W/mK. In someembodiments, the thermal conductivity in the thickness direction is atleast 2.5 W/mK, or at least 3 W/mK, or at least 3.5 W/mK.

In some embodiments, a layer or film (e.g., 2080, 2180, 2280, 2380, orlayers or films described elsewhere herein) has first and secondelectrical conductivities (e.g., corresponding to α₂ and α₃ of FIGS. 24and 24A) along substantially mutually orthogonal respective first (e.g.,z) and second (e.g., y) directions, where the first and seconddirections are substantially parallel to at least one cross-section(e.g., y-z cross-section and/or a cross-section where the particles havealternating higher and lower densities). In some embodiments, the firstelectrical conductivity is greater than the second electricalconductivity by at least a factor of 2. In some embodiments, the layerhas an electrical resistance in the thickness direction of less thanabout 1 ohm, or less than about 0.3 ohms, or less than about 0.1 ohm.The electrical resistance in the thickness direction can be in a rangeof about 0.005 ohms to about 0.5 ohms, or about 0.01 ohms to about 0.1ohms, for example. Electrical resistance can be measured as described inU.S. Pat. Appl. Pub. No. 2009/0359862 (Fang et al.).

In some embodiments, a layer or film (e.g., 2080, 2180, 2280, 2380, orlayers or films described elsewhere herein) has first and second realparts of relative permeabilities µʹ_(a) and µʹ_(b) (e.g., correspondingto α₂ and α₃ of FIGS. 24 and 24A) along substantially mutuallyorthogonal respective first (e.g., z) and second (e.g., y) directions,where the first and second directions are substantially parallel to atleast one cross-section (e.g., y-z cross-section and/or a cross-sectionwhere the particles have alternating higher and lower densities). Insome embodiments, for at least one frequency, µʹ_(a) is greater thanµʹ_(b) by at least 5 percent or at least 8 percent. The at least onefrequency can be less than 100 GHz, in a range of 1 MHz to 100 GHz, orin a range of 10 GHz to 50 GHz, for example. The at least one frequencycan be an operating frequency (e.g., 33.25 GHz) of a system includingthe layer, for example. In some embodiments, a layer or film (e.g.,2080, 2180, 2280, 2380, or layers or films described elsewhere herein)has first and second real parts of relative permeabilities µʹ_(c) andµʹ_(d) (e.g., corresponding to α₁ and α₃ of FIGS. 24 and 24A) alongsubstantially mutually orthogonal respective first (e.g., x) and second(e.g., y) in-plane directions. In some embodiments, for the at least onefrequency, µʹ_(c) is greater than µʹ_(d) by at least 5 percent or atleast 8 percent. In some embodiments, the layer or film has first andsecond imaginary parts of relative permeabilities µʺ_(c) and µʺ_(d)(e.g., corresponding to α₁ and α₃ of FIGS. 24 and 24A) alongsubstantially mutually orthogonal respective first and second in-planedirections, where for the at least one frequency, µʺ_(c) is greater thanµʺ_(d) by at least 5 percent or at least 8 percent. In some embodiments,the layer or film has first and second real parts of relativepermittivities εʹ_(c) and εʹ_(d) (e.g., corresponding to α₁ and α₃ ofFIGS. 24 and 24A) along substantially mutually orthogonal respectivefirst and second in-plane directions, where for the at least onefrequency, εʹ_(c) is greater than εʹ_(d) by at least 15 percent or atleast 20 percent. In some embodiments, the layer or film has first andsecond imaginary parts of relative permittivities εʺ_(c) and εʺ_(d)(e.g., corresponding to α₁ and α₃ of FIGS. 24 and 24A) alongsubstantially mutually orthogonal respective first and second in-planedirections, where for the at least one frequency, εʺ_(c) is greater thanεʺ_(d) by at least 15 percent or at least 30 percent.

In some embodiments, a magnetic film (e.g., corresponding to layers orfilms 2080, 2180, 2280, 2380, or layers or films described elsewhereherein)) has opposing first (10) and second (20) major surfaces and aplurality of magnetically permeable particles (e.g., particles 30)dispersed therebetween. The particles are so arranged to define mutuallyorthogonal in-plane first (e.g., x-direction, or direction along layersof particles) and second (e.g., y-direction, or direction orthogonal tolayers of particles) directions of the film. FIGS. 45 and 45A areschematic top views of a transmission line 741 that can be used fortesting a layer or film 780 where the first direction 747 of the layeror film 780 is indicated. In some embodiments, when the first majorsurface of the magnetic film is disposed on, and substantially parallelto, a transmission line 741 elongated along a length direction 746 andincluding opposing first (742) and second (744) ports, and a signal 743at a first frequency f1 greater than about 10 GHz, or in a range ofabout 10 GHz to about 30 GHz or to about 20 GHz, is applied to the firstport 742, a transmission coefficient (e.g., the S12 parameter of FIG.45D) of the transmission line 741 is Ta (in dB) when the first direction747 is substantially parallel to the length direction and Tb (in dB)when the first direction is substantially orthogonal to the lengthdirection. In some embodiments, Ta / T2 ≥ 1.3.

In some embodiments, the alternating higher and lower densities of theparticles results in the layer or film having an improved flexibilitycompared to a layer having a uniform distribution of the particles whenbent around an axis parallel to the x-axis, for example. This can beuseful for applying the layer or film on a curved surface, for example.

In some embodiments, a layer or film 2280 includes a plurality ofsubstantially continuous layers 43 of particles generally extendingalong orthogonal first (e.g., x) and second (e.g., z) directions andarranged along a third (e.g., y) direction, where each substantiallycontinuous layer 43 of particles includes a plurality of first particles30 having a first composition and a plurality of second particles 32having a different second composition. Each pair 43 a, 43 b of adjacentsubstantially continuous layers 43 of particles defines a space 46therebetween. Each of the first and second particles have a lowerdensity in the space 46 between, than in each of, the layers 43 ofparticles. In some embodiments, one or more (e.g., a majority) of thesubstantially continuous layers 43 of particles includes first (27) andsecond (29) regions interspersed with one another where the firstregions 27 have a higher density of the first particle 30 and a lowerdensity of the second particles 32, and the second regions have a higherdensity of the second particle 32 and a lower density of the firstparticle 30. In some embodiments, at least some of the first regions 27include only a single particle. In some embodiments, at least a majorityof the second regions 29 include a plurality of the second particles 32.In some embodiments, at least a majority of the second regions 29 arefree from first particles 30. FIG. 54A shows a first region containing asingle first particle and disposed between adjacent second regions eachcontaining a plurality of second particles.

In some embodiments, a layer or film 2380 includes a plurality ofalternating layers 41, 44, of first (30) and second (32) particles,respectively, where the alternating layers 41, 44 generally extend alongorthogonal first (e.g., x) and second (e.g., z or z′) directions and arearranged along a third (e.g., y) direction. The first (30) and second(32) particles have different compositions.

In some embodiments, a layer or film includes pluralities of first andsecond particles having respective real parts of relative magneticpermeability µʹ₁ and µʹ₂. In some embodiments for at least one frequencyless than about 1 GHz, µʹ₁ / µʹ₂ ≥ 5. In some embodiments, the at leastone frequency includes 1000 Hz. In some embodiments, the at least onefrequency includes a frequency less than 10 Hz (e.g., 1 Hz). In anyembodiment where a magnetic or electrical property is specified for atleast one frequency less than about 1 GHz, the at least one frequencycan be or include 1000 Hz, 100 Hz, 10 Hz, and/or 1 Hz.

In some embodiments, the layer or film (e.g., 2080, 2180, 2280, 2380, orlayers or films described elsewhere herein) has a total volume loadingof particles less than about 70 percent, or less than about 60 percent,or less than about 55 percent, or less than about 50 percent, or lessthan about 45 percent, or less than about 40 percent, or less than about35 percent, or less than about 30 percent. In some embodiments, thetotal volume loading is greater than about 25 percent, or greater thanabout 30 percent, or greater than about 35 percent, or greater thanabout 40 percent, or greater than about 45 percent. The desired volumeloading typically depends on the size and/or shape of the particles, onhow many types of particles are included, and on desired properties ofthe layer or film. For example, in some embodiments, a total volumeloading of less than about 35 percent is used when roughly spherical orirregular shaped magnetic particles are utilized since a higher volumeloading can result in reduced ordering of the particles when a magneticfield is applied. In some embodiments, first and second particles areincluded, where the first particles are magnetically responsive flakes.It has been found that for some such embodiments, or for otherembodiments, a total volume loading of the first particles in the rangeof about 1 percent to about 20 percent, or about 2 percent to about 12percent, or about 2.5 percent to about 10 percent is a suitable loadingto provide a desired ordering and/or alignment and/or positioning of thesecond particles (e.g., the first particles can cause the secondparticles to at least partially align). In some such embodiments, or inother embodiments, a total volume loading of the first and secondparticles is less than about 55 percent. In some embodiments, the secondparticles are also flakes (e.g., electrically and/or thermallyconductive flakes). In some such embodiments, or in other embodiments, atotal volume loading of the first and second particles is in a range ofabout 20 percent or about 25 percent to about 55 percent or to about 50percent. In some embodiments, the second particles are substantiallyspherical, substantially spheroidal, or substantially spheroidal (e.g.,electrically and/or thermally conductive spheres). In some suchembodiments, or in other embodiments, a total volume loading of thefirst and second particles is in a range of about 40 percent to about 70percent, or about 45 percent to about 60 percent. In some embodiments,the first and second particles are dispersed in a polymeric matrix(e.g., binder 70), where the polymeric matrix includes at least 50percent by volume of the thermal interface layer.

In some embodiments, a thermal interface layer includes pluralities offirst and second particles dispersed in a polymeric binder at a totalloading V in a range of about 40 volume percent to about 70 volumepercent, and the thermal interface layer has a thermal conductivity in athickness direction of the thermal interface layer in units of W/mK ofat least K = 5.1 - 0.17 V + 0.002 V² (see, e.g., FIG. 55 ). For example,at a volume loading of V = 60 volume percent, K = 5.1 -0.17*60+0.002*60² = 2.1 W/mK. A ratio of a total volume of the first particlesto a total volume of the first and second particles can be in a range ofabout 0.04 to about 0.1 (see, e.g., FIG. 56 ). In some embodiments, thesecond particles are at least partially aligned so as to increase athermal conductivity of the thermal interface layer by at least 10percent (e.g., as compared to unaligned or randomly distributed secondparticles). In some embodiments, the second particles are at leastpartially aligned so as to increase a thermal conductivity of thethermal interface layer by at least 20 percent, or at least 25 percent,or at least 30 percent (see, e.g., FIG. 56 ).

FIG. 28 is a schematic top view of a layer or film 2480. In someembodiments, a layer of film 2480 includes particles agglomerated so asto form a plurality of substantially continuous layers 61 of particlesgenerally extending along orthogonal first (e.g., x) and second (e.g., zor z′) directions and arranged along a third direction (e.g.,y-direction). In some such embodiments, at least one (61 a) of thesubstantially continuous layers 61 of particles splits at a fork 71 intofirst (62) and second (63) sublayers. Each sublayer 62, 63 generallyextends along the first and second directions. The second sublayer 63can merge with an adjacent substantially continuous layer 61 b, forexample. In some embodiments, the plurality of substantially continuouslayers 61 of particles are spaced apart except for discrete regionswhere a sublayer of particles from one layer merges with another layer.

In some embodiments, a layer or film includes particles dispersedbetween opposing first and second major surfaces of the layer or filmwhere the particles are agglomerated so as to form a plurality of layersof particles generally extending along orthogonal first and seconddirections and arranged along a third direction, where each layer ofparticles extends from the first to the second major surface. The layershave a thickness along a fourth direction (e.g., y-direction) orthogonalto the first and second directions. FIG. 29 is a schematiccross-sectional view of a layer or film 2580 including layers 73 ofparticles (schematically indicated by solid lines indicating approximateboundaries of the layers) that have a smaller thickness near the firstmajor surface 10 and a larger thickness near the second major surface20. FIG. 30 is a schematic cross-sectional view of a layer or film 2680including layers 83 of particles (schematically indicated by solid linesindicating approximate boundaries of the layers) that have a smallerthickness near the first major surface 10 and a larger thickness nearthe second major surface 20. Near the first major surface 10, but notthe second major surface 20, the particles agglomerate with the layer 83so as to form alternating higher (84) and lower (85) density regions.Layers such as those depicted in FIGS. 29-30 can result from flow due togravity between the time that the layers of particles are formed and thetime that the polymeric binder is cured, for example.

FIG. 31 is a schematic side view of a layer or film 2780 includinglayers 41 of particles 30 dispersed in a binder 70 (e.g., a polymericmatrix and/or an adhesive) between first and second major surfaces 10and 20. The particles 30 have alternating higher (40) and lower (50)densities. The layer or film 2780 has alternating thicker (80) andthinner (90) regions corresponding to the alternating higher (40) andlower (50) densities. The first and second major surfaces 10 and 20 arestructured due to the alternating higher (40) and lower (50) densities.In some embodiments, each pair of adjacent substantially continuouslayers 41 of particles 30 defines a space 46 therebetween, where theparticles having a lower density in the space between, than in each of,the layers of particles. The particles 30 can optionally include firstand second particles as described further elsewhere herein. In someembodiments, the layer of film 2780 has alternating thicker (80) andthinner (90) regions where the thicker regions 80 are defined by thesubstantially continuous layers 41 of particles and the thinner regions90 are defined by the spaces 46 between adjacent substantiallycontinuous layers 41 of particles. The alternating thicker (80) andthinner (90) regions can result from shrinkage of the binder 70 when itis cured. For example, the binder 70 can be an ultraviolet (UV) curedacrylic resin that shrinks when cured. Any embodiment described hereinwhere particles form layers can have a similar structure. The particles30 can be magnetic particles and/or thermally and/or electricallyconductive particles. In some embodiments, the layer or film 2780 is anadhesive layer (e.g., a pressure sensitive adhesive layer). In some suchembodiments, the thinner, lower density regions provide good bondingwhile the thicker, higher density regions provide a “spring like effect”as the adhesive holds the particles to the surface in compressionallowing for improved performance (e.g., improved electrical or thermalcontact).

In some embodiments, the first and/or second particles include flakes.Flakes generally extend in orthogonal first and second direction andhave a thickness substantially smaller than dimensions along the firstand second directions. FIG. 32 is a schematic cross-sectional view of aflake 66 extending generally along orthogonal first (u) and second (v)directions defining a plane 68 of the flake 66. An orthogonal directionw is also illustrated. The plane 68 is parallel to the u-v plane and canbe taken to pass through a centroid of the flake 66. In someembodiments, a ratio of a maximum dimension of the flake in the plane ofthe flake to a thickness of the flake is at least about 3, 5, 8 or 10.

FIG. 33 is a schematic cross-sectional view of a layer or film 2880including a plurality of first flakes 830. The layer or film 2880 canfurther include a plurality of second particles which can include aplurality of second flakes and/or a plurality of substantially sphericalor irregular shaped particles, for example. FIG. 33A is a schematiccross-sectional view of a layer or film 2880A corresponding to layer orfilm 2880 but also including a plurality of second flakes 832. Eachfirst flake 830 extends generally along orthogonal first (e.g., u) andsecond (e.g., v) directions defining a plane (e.g., plane 68 of FIG. 32) of the first flake 830. In some embodiments, each first flake 830 inat least a majority of the first flakes is oriented such that the planeof the first flake makes an angle θ of less than 40 degrees, or lessthan 30 degrees, or less than 20 degrees, or less than 10 degrees withthe thickness direction of the layer or film. In some embodiments, eachfirst flake 830 in at least 70 percent of the first flakes is orientedsuch that the plane of the first flake makes an angle θ of less than 30degrees with the thickness direction of the layer or film. The sameplane 833 and the thickness direction (z-direction) can make an angleless than 30 degrees, or less than 20 degrees, or less than 10 degreestherebetween. Similarly, in some embodiments including second flake 832,each second flake 832 extends generally along orthogonal first (e.g., u)and second (e.g., v) directions defining a plane (e.g., plane 68 of FIG.32 ) of the second flake 832. In some embodiments, each second flake 832in at least a majority of the second flakes is oriented such that theplane of the second flake makes an angle θ2 of less than 40 degrees, orless than 30 degrees, or less than 20 degrees, or less than 10 degreeswith the thickness direction of the layer or film. In some embodiments,the first and/or second flakes are approximately parallel to one anotherand to a common plane. In some embodiments, each first flake 830 in atleast a majority of the first flakes is oriented such that the plane ofthe first flake makes an angle α of less than 40 degrees, or less than30 degrees, or less than 20 degrees, or less than 10 degrees with a sameplane 833. In some embodiments, each second flake 832 in at least amajority of the second flakes is oriented such that the plane of thesecond flake makes an angle of less than 40 degrees, or less than 30degrees, or less than 20 degrees, or less than 10 degrees with the sameplane 833.

In some cases, a partial alignment and/or ordering and/or positioning ofthe flakes 830, and a partial alignment and/or ordering and/orpositioning of the second particles caused by the flakes 830, issufficient to provide enhanced properties (e.g., increased thermalconductivity in the thickness direction). In other embodiments, a higherdegree of alignment and/or ordering and/or positioning of the flakes andsecond particles is preferred.

FIG. 34 is schematic cross-sectional view of a layer or film 2980including a plurality of first flakes 830, a plurality of secondparticles 832 (which are schematically illustrated as sphericalparticles, but which could alternatively be second flakes), and aplurality of optional third particles 836, and a plurality of optionalfourth particles 839. The particles are agglomerated into alternatingfirst (841) and second (842) layers, which can each be substantiallycontinuous layers of particles. The first layers 841 are formedprimarily from the first flakes 830 and the second layers 842 are formedprimarily from the second particles 832 and the third particles 836. Thethird particles 836 may be conductive particles (e.g., thermally and/orelectrically conductive) included to increase the conductivity of thelayer. In some embodiments, the third particles 836 are substantiallysmaller than the second particles 832 (e.g., the third particles 836 canhave a D50 less than 0.5, or 0.3, or 0.2 times a D50 of the secondparticles 832). In some embodiments, the fourth particles 839 aresubstantially smaller than the third particles 836 (e.g., the thirdparticles 836 can have a D50 less than 0.5, or 0.3, or 0.2 times a D50of the second particles 832). The layer of film 2980 can alternativelybe described (e.g., when the optional particles 836 and 839 are includedand have a same composition as particles 832) as including firstparticles 830 and second particles where the second particles includeparticles 832, 836, and 839. In this case, the second particles have amultimodal particle size distribution. In some embodiments, only one ofthe pluralities of particles 836 and 839 are included so that the secondparticles have a bimodal size distribution. In some embodiments, threeor more, or four or more different size particles are included. Secondparticles (e.g., alumina or boron nitride) having a multimodal sizedistribution has been found, for example, to improve the thermalconductivity in a thermal interface layer, for example. The firstparticles (e.g., the magnetic particles) can also optionally have amultimodal particle size distribution.

The particles 832, 836, and 839 may be substantially spherical, or theparticles may be flakes, or some particles may be spherical and otherparticles may be flakes, or other particle shapes (e.g., substantiallyspheroidal or substantially ellipsoidal) may be used. In someembodiments, the second particles include flakes (e.g., corresponding toparticles 832 and optionally 836) and particles 839, which may besubstantially spherical, substantially spheroidal, or substantiallyellipsoidal, for example, are used as bridging particles to increase thethermal or electrical conduction between the flakes, for example.

FIGS. 34A-34B are schematic illustration of multimodal particle sizedistributions (e.g., distribution of diameter approximately sphericalparticles or distribution of diameter or largest lateral dimensions offlakes). A multimodal particle size distribution can have 2 (bimodal),3, 4, or more peaks. FIG. 34A schematically illustrates a bimodalparticle size distribution 655 while FIG. 34B schematically illustratesa particle size distribution 657 having 4 peaks.

FIGS. 35 and 35A are schematic cross-sectional views of a plurality ofmagnets 914 positioned proximate a web 911. In FIG. 35 , each magnet hasa same north pole orientation (the north pole faces the +z direction andthe south pole faces the -z direction). In FIG. 35A, the plurality ofmagnets has alternating first (e.g., +z) and second (e.g., -z) northpole orientations. In the illustrated embodiment, the first north poleorientation (oriented in +z direction) is opposite the second north poleorientation (oriented in -z direction). In some embodiments, the magnets914 are substantially cylindrical magnets having an average diameter d1.In some embodiments, the magnets 914 are spaced apart with an averagecenter to center distance s1. In some embodiments, s1/d1 is at leastabout 3, 5, 8 or 10. In some embodiments, the plurality of magnets 914is or includes a regular array of cylindrical magnetics.

Arrangements of (e.g., static) magnets as schematically illustrated inFIGS. 35 and 35A are useful in producing layers or films havingpartially ordered and/or aligned and/or positioned particles asillustrated for layer or film 2880, for example. As described furtherelsewhere herein, rotating magnetics are useful producing layers orfilms having particles with improved order and/or alignment and/orpositioning, as schematically illustrated for layer of film 2980, forexample. In some embodiments, a plurality of substantially parallel,spaced apart rotating magnets is used (e.g., to further improvealignment/orientation/positioning of the particles in the layer comparedto using a single rotating magnet, or to increase line speed whilemaintaining alignment/orientation/positioning of the particles). Forexample, the magnets 914 schematically illustrated in FIGS. 35 and 35Ainstead of having a fixed north pole/south pole alignment canalternatively be rotated about their axis as the web 911 passes by themagnets.

In some embodiments, a method of making a film includes positioning aplurality of magnets 914 relative to a web 911 containing a mixture of aplurality of magnetic particles dispersed in a resin. The web 911extends generally along a first direction (x-direction) and has a widthalong an orthogonal second direction (y-direction). Each magnet iselongated along an axis (e.g., x-axis) not parallel to the firstdirection. For example, in some embodiments, the axis of each magnet issubstantially orthogonal to the first direction. The plurality ofmagnets 914 are spaced apart along the first direction. The methodincludes passing the web 911 adjacent the plurality of magnets 914(e.g., by moving the web 911 along the first direction when the web isadjacent the magnets 914) such that the magnetic particles areinfluenced by a magnetic field of the plurality of magnets 914 and forma desired structure as affected by the magnetic field. The methodfurther includes vitrifying the resin to capture the plurality ofmagnetic particles in the desired structure.

As described further elsewhere, in some embodiments, a method of makinga film include positioning a magnet relative to a web containing atleast a mixture of a plurality of magnetic particles dispersed in aresin. The web extends generally along a first direction and having awidth along an orthogonal second direction. The magnet is elongatedalong an axis not parallel to the first direction. The method includesrotating the magnet about the axis such that a north pole and a southpole of the magnet alternatively pass in proximity of the web. Themethod includes passing the web adjacent the magnet such that themagnetic particles are influenced by a magnetic field of the magnet andform a desired structure as affected by the magnetic field. The methodfurther includes vitrifying the resin to capture the plurality ofmagnetic particles in the desired structure.

The web 911 can move in the x direction in a roll-to-roll process, forexample.

FIGS. 36 and 36A are schematic top views of magnets 1014 a and 1014 b,respectively positioned adjacent a web 1011. The magnet 1014 a has alength La along its axis and the magnet 1014 b has a length Lb along itsaxis. A plurality of magnets can be included and/or the magnet(s) canrotate as described further elsewhere herein. In some embodiments, eachmagnet has a length along the axis that is at least ½ the width of theweb, or at least the width of the web. In some embodiments, the web 101has opposite first (1037) and second (1038) edges separated from oneanother along the second direction (y-direction) and each magnet 1014 bextends at least from the first edge 1037 to the second edge 1038 asschematically illustrated in FIG. 36A.

The layers or films described herein can be a single layer, a singlelayer film or a multilayer film. FIG. 37 is a schematic cross-sectionalview of a film 3180 including layer 3080 which includes a plurality ofparticles (not shown in FIG. 37 ) and additional layers 3081 and 3082.Additional layers 3081 and 3082 can be carrier layers or release layers,for example. In some embodiments, film 3180 is one or more of a magneticfilm, an electrically conductive tape, or a thermal interface film (afilm including a thermal interface layer). In some embodiments, film3180 is an electrically conductive tape, layer 3082 is a tape backinglayer, layer 3081 is release layer, and layer 3080 is an electricallyconductive adhesive layer.

FIG. 37A is a schematic cross-sectional view of a film 3380 includinglayer 3280, which includes a plurality of particles (not shown in FIG.37A) and a fabric 3383. The film 3380 further includes additional layers3081 and 3082, which can be carrier layers or release layers, forexample. In some embodiments, film 3380 is one or more of a magneticfilm, an electrically conductive tape, or a thermal interface film. Thefabric 3383 can be included to provide mechanical strength to the layer3280. In some embodiments, the fabric 3383 is at least one ofelectrically or thermally conductive. In some embodiments, film 3380 isan electrically conductive tape, layer 3382 is a tape backing layer,layer 3381 is release layer, and layer 3280 is an electricallyconductive adhesive layer. Electrically conductive tapes are describedin US 2016/0333232 (Choi et al.), for example, which is herebyincorporated herein by reference to the extent that it does notcontradict the present disclosure. Suitable adhesive materials (e.g.,PSAs) for use in an adhesive layer are described in US 2016/0333232(Choi et al.), for example.

FIG. 38 is a schematic perspective view of a roll 3333 of layer or film3334. The layer or film 3334 can be a magnetic film, can include anelectrically conductive adhesive layer, and/or can be or include athermal interface layer. In some embodiments, a layer or film 3334 isrolled along a length of the layer or film 3334 to form a roll 3333. Insome embodiments, as described further elsewhere herein, the film, or alayer of the film, includes a plurality of substantially continuouslayers of particles extending along the length and a thickness of thefilm or the layer and arranged along a width of the film or the layer.In some embodiments, the film 3334 has a substantially higher (e.g.,higher by at least 5 percent, or at least 8 percent) magneticpermeability along each of the thickness and the length of the film thanthe width of the film. The magnetic permeability can be a real part of acomplex magnetic permeability for at least one frequency less than about1 GHz. In some embodiments, the layer or film 3334 is or includes anelectrically conductive adhesive layer having a substantially higherelectrical conductivity along each of the thickness and the length ofthe layer than the width of the layer. For example, the electricalconductivity can be at least a factor of 1.4, or 1.7, or 2, or 2.5 timeshigher along each of the thickness and the length of the layer than thewidth of the layer. In some embodiments, the layer or film 3334 is orincludes a thermal interface layer having a substantially higher thermalconductivity along each of the thickness and the length of the layerthan the width of the layer. For example, the thermal conductivity canbe at least a factor of 1.4, or 1.7, or 2, or 2.5 times higher alongeach of the thickness and the length of the layer than the width of thelayer.

In some embodiments, a layer includes first (10) and second (20) majorsurfaces spaced apart a distance D in a thickness direction of the layerand has a lateral length L along a length direction of the layerorthogonal to the thickness direction (see, e.g., FIG. 24 ). In somesuch embodiments, L/D ≥ 100. The layer can include a plurality ofparticles 30 dispersed and asymmetrically distributed between the firstand second major surfaces so that in each of at least a first layercross-section (e.g., y-z cross-section) of the layer orthogonal to thelength direction and a second layer cross-section (e.g., x-ycross-section) of the layer orthogonal to the thickness direction, anellipse fitted to a cross-section of a two dimensional autocovariance ofan image of the layer cross-section at 10% of a central peak of theautocovariance has a major axis length L1 and a minor axis length L2. Asis known in the art, an autocovariance is an average of a product of avariable multiplied by the same variable evaluated at a different point.The autocovariance of a quantity can be determined as the real part ofthe Fourier transform of the power spectral density of the quantity. Asis known in the art, a power spectral density of a quantity is themagnitude squared of the Fourier transform of the quantity.Autocovariance of an image can be determined using standard processingtechniques (e.g., using functions available in MATLAB). In some suchembodiments, L1/L2 ≥ 1.2. The plurality of particles 30 can beasymmetrically distributed between the first and second major surfacesin any manner which results in autocovariances as described above. Insome embodiments, the plurality of particles 30 are asymmetricallydistributed by being agglomerated into substantially continuous layersof particles, for example, so that the distribution of particles isdifferent along different directions. For example, the particles 30 canhave a different distribution along the y-direction (see, e.g., FIG.24A) than along the x-direction (see, e.g., FIG. 24 ).

FIG. 39 is a schematic plot of an autocovariance of an image of a layercross-section. 10% of a central peak 3901 is indicated. FIG. 39A is aschematic cross-section of a two dimensional autocovariance 3903 of animage of the first layer cross-section at 10% of the central peak 3901of the autocovariance. FIG. 39B is a schematic cross-section of a twodimensional autocovariance 3905 of an image of the second layercross-section at 10% of the central peak 3901 of the autocovariance. Insome embodiments, an ellipse 3904 and/or 3906 fitted to the first and/orsecond cross-section, respectively has a major axis length L1 and aminor axis length L2, where L1/L2 ≥ 1.2. In some embodiments, the majoraxis of the ellipse corresponding to the first layer cross-section (seeFIG. 39A) makes an angle β1 between about 10 degrees to about 50 degreeswith the thickness direction. In some embodiments, the major axis of theellipse corresponding to the second layer cross-section (see FIG. 39B)makes an angle β2 between about 10 degrees to about 50 degrees with thethickness direction.

In some embodiments, L1/L2 ≥ 1.5, or L1/L2 ≥ 2, or L1/L2 ≥ 2.5.

In some embodiments, a layer includes first (10) and second (20) majorsurfaces spaced apart a distance D in a thickness direction of the layerand has a lateral length L along a length direction of the layerorthogonal to the thickness direction (see, e.g., FIG. 24 ). In somesuch embodiments, L/D ≥ 100. The layer can include plurality ofparticles (e.g., 30) dispersed between the first and second majorsurfaces and regularly arranged so that in each of at least a firstlayer cross-section (e.g., y-z cross-section) of the layer orthogonal tothe length direction and a second layer cross-section (e.g., x-ycross-section) of the layer orthogonal to the thickness direction, apower spectral density of a positive portion of a two dimensionalautocovariance of an image of the layer cross-section has a peakcorresponding to a pitch of less than about 100 micrometers andcorresponding to the regular arrangement of the particles. The particlescan be regularly arranged by being agglomerated into substantiallycontinuous layers of particles, for example, where the layers ofparticles are regularly arranged along the width direction (see, e.g.,the y-direction of FIG. 24A), for example.

FIG. 39C is a schematic plot of a positive portion of a two dimensionalautocovariance of an image of a layer cross-section. FIG. 39D isschematic plot of a power spectral density (PSD) of a positive portionof a two dimensional autocovariance of an image of the layercross-section having a peak 3910 at a spatial frequency F1. The spatialfrequency F1 can correspond to a pitch P = 1/F1 where the pitch P can beless than about 100 micrometers (e.g., in a range of 1 to 100micrometers or 1 to 80 micrometers, or 2 to 50 micrometers, or 4 to 40micrometers).

FIG. 39E is an image of a layer cross-section of a layer orthogonal tothe thickness direction. The layer of FIG. 39E includes iron particlesin resin that has been subjected to a rotating magnetic field. FIG. 39Fis a two dimensional autocovariance of the image of the layercross-section of FIG. 39E at 10% of a central peak of theautocovariance.

FIG. 39G is a plot showing a yPSD (the PSD of a positive portion of atwo dimensional autocovariance integrated over the full range in thex-direction (length direction) and averaged over four PSD curves; theyPSD is a function of the spatial frequency in the x direction (widthdirection)) for the layer cross-section of FIG. 39E (curve 3931), for alayer cross-section of a layer including iron particles in resin thathas been subjected to a static magnetic field (curve 3932), and for alayer cross-section of a layer including iron particles in resin thathas not been subjected to a magnetic field (curve 3933).

The layer (e.g., the layer referred to in any of FIGS. 39-39F or otherlayer described herein) can be a magnetic layer, an electricallyconductive adhesive layer, and/or a thermal interface layer, forexample. In some embodiments, at least some of the particles aremagnetically permeable. In some embodiments, at least some of theparticles are electrically conductive. In some embodiments, at leastsome of the particles have a thermal conductivity of at least 10 W/mK.For example, at least some of the particles have a thermal conductivityof at least 10 W/mK along at least one direction, or along each of twoorthogonal directions, or along each of three mutually orthogonaldirections.

FIG. 40 is a schematic cross-sectional view of a system 2000 forwireless power transmission. The system includes a power receivingassembly 3000 including a first magnetic film 3010 disposed between afirst metal plate 3020 and a power receiving antenna 3030; and a powertransmitting assembly 4000 facing the power receiving assembly 3000 andincluding a second magnetic film 4010 disposed between a second metalplate 4020 and a power transmitting antenna 4030. The power receivingand transmitting antennas face, and are substantially aligned with, oneanother (e.g., the antennas may extend in respective planes which arewithin 30 degrees, or within 20 degrees, or within 10 degrees of beingparallel to one another), such that when energized, the powertransmitting antenna 4030 wirelessly transmits power to the powerreceiving antenna 3030. At least one of the first and second magneticfilms is a magnetic film of the present disclosure (e.g., includingmagnetic particles agglomerated into layers). In some embodiments, thesystem 2000 is configured to operate at an operating frequency, whereatthe operating frequency, a real relative magnetic permeability of themagnetic film has a first value µ'₁ along a separation direction(x2-direction) between the power receiving and transmitting assembliesand a second value µ'₂ along a second direction (e.g., one ofx1-direction and x3-direction) orthogonal to the separation direction,where µ'₁ is greater than µ'₂ by at least 5%.

EXAMPLES Materials

Material Description Supplier Sendust HS80 ~80 µm × 1 µm magneticallyresponsive flake, thermal conductivity of ~80 W/mK Mate Co., Ltd.,Okayama, JP 500-15 BN Flake Boron nitride (BN) flake available under thetrade designation Flakes CFF 500-15, D50 of 160-400 µm, thermalconductivity of 3-5 W/mK (through-plane) and 100-400 W/mK (in-plane) 3MCompany, St. Paul, MN 500-3 BN Flake Boron nitride (BN) flake availableunder the trade designation Flakes CFF 500-3, D50 of 300-530 µm, D10 of140-260 µm 3M Company, St. Paul, MN 200-15 BN Flake BN flake availableunder the trade designation Flakes CFF 200-15, D50 of 65-210 µm, thermalconductivity of 3-5 W/mK (through-plane) and 100-400 W/mK (in-plane) 3MCompany, St. Paul, MN AA-18 Polyhedral alumina, D50 of 18 µm, thermalconductivity of ~40 W/mK Sumitomo Chemical, Tokyo, JP TM1250 Alphaalumina powder, D50 of 1.6 µm, thermal conductivity of ~40 W/mK HuberEngineered Materials, Atlanta, GA Platelets 012P Spray dried BNplatelets available under the trade designation Platelets CFP 012P, D10of 65-120 µm, D50 of 125-190 µm, D90 of 200-300 µm, thermal conductivityof 3-5 W/mK (through-plane) and 100-400 W/mK (in-plane) 3M Company, St.Paul, MN Asbury 3268 Graphite flake, D50 of ~180 µm Asbury Carbons BAK70Spherical alumina, D50 of 70 µm, thermal conductivity of ~30-40 W/mKBestry BAK10 Spherical alumina, D50 of 10 µm, ~30-40 W/mK Bestry NGR-80Nickel coated graphite (60 wt% Nickel), avg. size of 115 µm PottersIndustries LLC, Valley Forge, PA DP460 Epoxy adhesive 3M Company, St.Paul, MN DER332 Epoxide resin OLIN EPOXY TEPA TetraethylenepentamineTokyo Chemical Industry IRGACURE 819phenylbis(2,4,6-Trimethylbenzoyl)-phosphine oxide, CAS#:162881-26-7 BASFCorporation, Evans City, PA iso-octyl acrylate iso-octyl acrylate,CAS#29590-42-9 3M Company, St. Paul, MN 1,6 hexanediol diacrylate 1,6hexanediol diacrylate TCI America N-dimethylacrylamideN-dimethylacrylamide TCI America DISPERBYK 145 Dispersing additive BYK,Wesel, Germany CIP-EW Carbonyl iron powder, D50 of 3-4 µm BASFCorporation, Evans City, PA CIP-ER Carbonyl iron powder, D50 of 4.5 µmBASF Corporation, Evans City, PA PNW-5-PCN(ii) 15 micrometer thicknonwoven scrim coated with thin layers of nickel/copper/nickelAjin-Electron Co., Ltd. Busan, ration, Rock Hill, SC SN40S15 Silvercoated nickel particles, 15 wt% silver, avg. size of 42 µm PottersIndustries LLC, Valley Forge, PA NG15F50 Nickel coated glass flakes,49.4 wt% Ni, D90 of 51.7 µm, D50 of 29.5 µm, D10 of 14.4 µm, mean sizeof 31.5 µm Potters Industries LLC, Valley Forge, PA E-Fill 2806 Nickelcoated graphite flake, D10 of 16 µm, D50 of 30 µm, D90 of 55 µm OerlikonMetco, Pfäffikon, Switzerland

Assembly of Magnetic Apparatus I

Three diametrically magnetized cylinder magnets (obtained as RY04YODIAfrom K&J Magnetic Inc., Pipersville, PA), each having an outer diameterof 50.8 mm, an inner diameter of 6.35 mm, and a length of 50.8 mm, wereaffixed to a 6.22 mm 304 stainless steel shaft with Epoxy Adhesive DP460with all north poles facing the same direction. This resulted ineffectively a single diametrically magnetized cylinder magnet with adiameter of 50.8 mm and a length of 152.4 mm. This resultant cylindermagnet was connected to an electric DC motor (obtained as Partno:3482-MAC5115 Rev. 1 with maximum speed 3450 rpm from AMETEK Pittman)to spin it about its axis. At the sample preparation position, themaximum magnetic field was about 2.2 kG.

Assembly of Magnetic Apparatus II

Magnetic Apparatus II was prepared as described for Magnetic Apparatus Iexcept that 6 of the diametrically magnetized cylinder magnets wereaffixed to the stainless steel shaft with all north poles facing thesame direction to form effectively a single diametrically magnetizedcylinder magnet with a diameter of 50.8 mm and a length of 304.8 mm. Themeasured field strength was 4.34 kG directly above the rotating shaft.The rotating shaft could be driven up to 2200 rpm.

Comparative Example C1 - Carbonyl Iron Powder (CIP) in Silicon Elastomer(SYLGARD 184)

In a plastic cup, SYLGARD 184 Part A (available from Dow) was degassedunder vacuum for 10-15 minutes. SYLGARD 184 Part B, the curing agent,was then added to the degassed Part A. The amounts of Parts A and B werechosen so that the Part A : Part B ratio was 10:1 by weight. To thismixture was added CIP-EW in an amount to result in a loading of about50% CIP-EW powder by weight. The plastic cup was covered with a capconfigured to allow speed mixing under vacuum (100 mbar) for 2 minutesand 15 seconds. The mixture was then poured onto an Aluminum plate. Asecond Aluminum plate was placed on top of the mixture and appropriatesilicon spacers (min 1.5 mm) were used between the two plates toseparate them to a desired thickness. The plates containing the mixturewere pressed together with 5 kg of weight on top. The Aluminum plateswere heated to 150° C. using heating strip and monitoring temperatureusing thermal couple. The plates were kept at 150° C. for 10 mins. Theplates were them allowed to cool for 30-45 minutes before the curedcomposite sheet was removed. The sheet had dimensions of about 10 cm by6 cm.

Example 1 - Carbonyl Iron Powder (CIP) in Silicon Elastomer (SYLGARD184)

A sample was made as in Comparative Example C1, except that afterplacing the sample between two aluminum plates with a 5 kg of weight ontop, the sample with the plates and with top weight was placed on theMagnetic Apparatus I. The diametrically magnetized cylinder magnet wasset to rotate at 40% of maximum speed. After 10 seconds, the Aluminumplates were heated to 150° C. using heating strip and temperature wasmonitored using a thermal couple. The plates were kept at 150° C. for 10mins. The plates were then allowed to cool for 30-45 minutes before thecured composite sheet was removed.

Comparative Example C2 - Carbonyl Iron Powder (CIP) in Polyurethane

92.5 parts of 3M SCOTCH-WELD PUR Adhesive 2710p (available from 3MCompany, St. Paul, MN), 7.4 parts of Hydroxyethylmethacrylate (from SanEster), and 0.1 part of 2,4,6-trimethylbenzoylphenyl phosphinate(IRGACURE TPO-L) was added to a black cup and heated up to 110° C. fortwo hours. Then the mixture was mixed using speed mixer for 3 mins.CIP-ER was added to the mixture in an amount to result in a loading of53.2% by weight of CIP-ER powder in the whole slurry which was thenmixed again under vacuum (100 mbar). The mixture was then poured onto anultraviolet (UV) light transparent glass. An ultraviolet (UV) lighttransparent glass was placed on top of the mixture and appropriatesilicon spacers (min 1.5 mm) were used between the two plates toseparate them to a desired thickness. The glasses containing the mixturewere pressed together with 5 kg of weight on top. The 5 kg weight wasremoved and the sample with glass plates was put on a DYMAX BLUEWAVE LEDFLOOD curing system (Dymax Corporation, Torrington, CT) with 100%intensity to cure the mixture with ultraviolet (UV) light irradiation(365 nm) for 25 seconds. The sample with the glasses plates was flippedover and the UV curing step was repeated.

Example 2 - Carbonyl Iron Powder (CIP) in Polyurethane

A sample was made as in Comparative Example C2, except that after theglass plates containing the mixture were pressed together with 5 kg ofweight on top, the whole assembly (sample, plates and top weight) wasplaced on the Magnetic Apparatus I. The diametrically magnetizedcylinder magnet was set to rotate at 40% of maximum speed. After 10seconds, the top weight was removed, and the sample was cured using theDYMAX BLUEWAVE LED FLOOD as described for Comparative Example C2.

Examples 3-4

Examples 3-4 were prepared as Example 1 except that the CIP-EW wasincluded in the layer at 60 wt% (17 volume percent) and 40 wt% (8.4volume percent), respectively. FIGS. 41-42 are images showing top andcross-sectional views of Example 3, respectively. FIGS. 43 and 43A areimages showing top views of Example 4 at different magnifications. FIGS.44 and 44A are images showing cross-sectional views of Example 4 atdifferent magnifications.

Comparative Example C3

Comparative Example C3 was prepared as Example 1 except that the CIP-EWwas included in the layer at 80 wt% (35.6 volume percent). Images showedthat the particles were randomly distributed in the layer and did notagglomerate into sheets.

Power Loss and Shielding Effectiveness Measurements

Samples were tested using a test fixture that included an about 3 mmwide micro-strip-line (schematically illustrated in FIGS. 45 and 45A)with 50 Ω impedance that was hooked to a ZNB20-Vector Network Analyzer(VNA) (from ROHDE&SCHWARZ) using coaxial radio frequency (RF) cables.The full 4-port calibration was performed on the VNA with cables. Asample was cut to 50 mm x 50 mm and then aligned to the strip-line andplaced on top of the micro-strip line. Styrofoam (dimension: Length xWidth x Height = 129 x 96 x 50 mm) and Teflon blocks (dimension: Lengthx Width x Height = 130 x 100 x 25 mm) were put on top of the testedsamples to press samples towards microstrip line. The Styrofoam blockwas between the sample and the Teflon block. The full 4 portS-parameters were measured for each sample and for the test fixturewithout a sample (empty). The test frequencies range was set to 300 kHzto 20 GHz. Shielding effectiveness was calculated as a difference inS21(measured in dB by VNA) parameters for test fixture loaded withsamples and without (empty). Preliminary Power loss were calculated asPL = 1-|S11|²-|S21|² for all samples and the empty test fixture. Thefinal reported PL is a difference between PL for the test fixture withsamples and without (empty).

FIG. 45B is a plot of a power loss versus frequency for various samples.FIG. 45C is a plot of shielding effectiveness versus frequency forvarious samples. FIG. 45D is a plot of the magnitude of the transmissioncoefficient (S12) versus frequency for various samples. “Parallel”indicates that the in-plane direction of the layers of particles in themagnetic film is parallel to the transmission line (as schematicallyillustrated in FIG. 45 ) while “perp” indicates that the in-planedirection of the layers of particles in the magnetic film isperpendicular to the transmission line (as schematically illustrated inFIG. 45A). “Empty” indicates that the sample was not present.

Comparative Example C4

An acrylate slurry was prepared as follows. 299.88 grams of iso-octylacrylate was mixed with 0.12 grams of IRGACURE 819 as photo initiatorand were introduced into a 1 L glass reactor. Then, the mixture waspartially polymerized by ultraviolet (UV) light irradiation (365 nm) toobtain syrup having a viscosity of about 900 cps. 87.58 gram of theprepared syrup was transferred into an 800 mL plastic cup, and 0.136grams of 1,6 hexanediol diacrylate, 37.43 gram of N-dimethylacrylamide,0.18 gram of IRGACURE 819 and 125.40 gram of NGR-80 was added to thecup. Then, the cup was put into a speed mixer to mix all the materialsuniformly under vacuum, resulting in a smooth slurry for coating. Theresulting slurry contained about 50 wt% NGR-80.

An adhesive film was made on a small lab coater with a two roll coaterset-up. A release liner RFO2N (SKC Hitech & Marketing Co., Ltd, Korea; 3mil thick) was on the bottom roll. Another release liner RF12N (SKCHitech & Marketing Co., Ltd, Korea; 3 mil thick) was on the top roll.These two liners were fed through the coating head and the coating gapbetween two liners was adjusted to 150 micrometers. A layer ofPNW-5-PCN(ii), a 15 micrometer thick electrically conductive nonwovenscrim coated with multiple, thin layers of metal, was placed onto thebottom liner and the beginning edge of the conductive nonwoven sheet wasfixed using polyimide tape to prevent from sliding relative to thebottom liner. Some of the Acrylate Slurry was poured onto the conductivenonwoven sheet and then the two release liners were pulled through thecoating header gap to provide the adhesive film.

An approximately 12 cm x 12 cm piece of the coated adhesive layer wascut out and cured with ultraviolet (UV) light irradiation (365 nm) byusing the device DYMAX bluewave LED FLOOD with 25% intensity for 25seconds (total energy: 1322mJ/cm2, power intensity:47.5mW/cm2). Thecoated adhesive layer was then flipped over and cured once more underthe same conditions.

Comparative Example C5

Comparative Example C5 was made as Comparative Example C4 except thatthe coated adhesive layer was placed on top of the Magnetic Apparatus Ifor 10 seconds while the diametrically magnetized cylinder magnet waskeept still. Then, the coated adhesive layer was cured in a similarmanner as Comparative Example C4.

Example 5

Example 5 was made as Comparative Example A1 except that the coatedadhesive layer was placed on top of the Magnetic Apparatus I for 10seconds while the diametrically magnetized cylinder magnet was rotatingat 20% of maximum speed. Then, the coated adhesive layer was cured in asimilar manner as Comparative Example C4. The adhesive layer was roughly500 micrometers thick. FIGS. 46 and 46A are images of top views of theadhesive layer at different magnifications. FIG. 46B is an image of across-section image of the adhesive layer.

Impedance Measurements

A measurement board which included a 3 mm wide micro-strip-line with 10mm gap was hooked to a ZNB20-Vector Network Analyzer (VNA) (fromROHDE&SCHWARZ) or to an Impedance Analyzer E4990A (20 Hz-120MHz) (fromAgilent Technologies). Two pieces of tape were cut to 3 mm x 15 mm andone was adhered to each end of a 3 mm x 40 mm x 1 mm stainless steel barafter removing one side liner. Then the stainless steel bar with tapewas aligned to the strip-line and gently adhered after removing anotherside liner. A 1 kg of weight was applied to the top of the stainlesssteel bar for 10 seconds. After resting for 20 minutes, the sample wasmeasured on the VNA or Impedance Analyzer.

FIGS. 47 and 47A are plots of the signal magnitude S11 (reflection byconductive adhesive layers) and S21 (transferred through z-direction ofconductive adhesive layers from port 1 to port 2), respectively, versusfrequency. The label “through” indicates that a metallic copper stripwith the same dimensions as the strip-line of the test fixture was usedin place of the sample. This was considered an “ideal” sample (veryhighly conductive) to compare the tape measurements to. The label “open”indicates that no sample was in the test fixture and that no tape orbridging stainless steel bar was included. This was considered areference for a worst case (no conduction).

FIGS. 47B and 47C are plots of the real and imaginary parts,respectively, of the impedance of the conductive adhesive layers versusfrequency.

Example 6

Example 6 was prepared as in Example 5 except that nickel coatedgraphite (E-Fill 2806) and silver coated nickel (SN40S15) were used inplace of NGR-80, and the nonwoven scrim was not included. The loading ofE-Fill 2806 was about 45.7 wt.% or 20 vol.% and the loading of SN40S15was about 20 wt. % or 5 vol.%. Samples were made with the diametricallymagnetized cylinder magnet rotating at 20% of maximum speed and at 40%of maximum speed. FIG. 48 is a top view image of a comparative samplethat was not subjected to a magnetic field, FIG. 48A is a top view imageof a sample made with a magnet rotation speed of 20% of maximum, andFIG. 48B is a top view image of a sample made with a magnet rotationspeed of 40% of maximum.

Example 7

Example 7 was prepared as in Example 5 except that silver coated nickel(SN40S15) was used in place of NGR-80, and the nonwoven scrim was notincluded. The loading of SN40S15 was about 74.2 wt.% or about 25 vol.%.Samples were made with the diametrically magnetized cylinder magnetrotating at 20% of maximum speed and at 40% of maximum speed. FIG. 49 isa top view image of a comparative sample that was not subjected to amagnetic field, FIG. 49A is a top view image of a sample made with amagnet rotation speed of 20% of maximum, and FIG. 49B is a top viewimage of a sample made with a magnet rotation speed of 40% of maximum.

Example 8

Example 8 was prepared as in Example 5 except that nickel coated glass(NG15F50) and silver coated nickel (SN40S15) were used in place ofNGR-80. Samples were made with and without the nonwoven scrim was notincluded. The loading of NG15F50 was about 36.6 wt.% or 19 vol.% and theloading of SN40S15 was about 26 wt.% or 6 vol.%. Samples were made withthe diametrically magnetized cylinder magnet rotating at 20% of maximumspeed. FIG. 50 is a top view image of a sample without the nonwovenscrim. FIG. 50A shows top view images of the sample at a lowermagnification on the left and a higher magnification on the right. Thesample made with the nonwoven scrim had a thickness of 94 micrometers, aresistance in the thickness direction of 0.05 ohms, a resistance in anin-plane direction along the layers of particles of 0.635 ohms, and aresistance in an in-plane direction perpendicular to the layers ofparticles of 1.70 ohms. The sample made without the nonwoven scrim had athickness of 103 micrometers and a resistance in the thickness directionof 0.06 ohms.

Example 9

The organic components indicated in the following table were added to a200-gram capacity speed mixer cup along with fillers and, for somesamples, DISPERBYK 145 as a dispersing agent (indicated under “Disp.?”in the table). The whole system was then mixed with the followingprotocol on a DAC 1100.2 VAC-P Speed Mixer (FlackTek) under thefollowing conditions:

-   1. 1200 RPM 20 sec, 300 mbar-   2. 1400 RPM 20 sec, 300 mbar

The fillers for each sample included Sendust as Filler 1 and the fillerlisted under “Filler 2” in the table.

Sample No. Filler 2 TEPA qty (g) DER332 qty (g) Filler 1 qty (g) Filler2 qty (g) Disp.? Vol. Fraction Filler Vol. Fraction Sendust 1 500-15 BNFlake 2.3 15.04 17.23 15.28 Y 0.40 0.10 2 500-15 BN Flake 2.53 16.5612.3 18.45 Y 0.40 0.07 3 500-15 BN Flake 2.7 17.65 7.97 21.54 Y 0.400.04 4 500-15 BN Flake 2.83 18.52 5.13 23.37 Y 0.40 0.03 5 500-15 BNFlake 2.01 13.16 18.36 16.29 Y 0.45 0.12 6 500-15 BN Flake 2.39 15.6 8.623.25 Y 0.45 0.05 7 500-15 BN Flake 2.89 18.86 11.3 16.95 Y 0.35 0.06 8500-15 BN Flake 2.89 18.86 11.3 16.95 N 0.35 0.06 9 200-15 BN Flake 2.3915.6 8.6 23.25 Y 0.45 0.05 10 500-3 BN Flake 2.39 15.6 8.6 23.25 Y 0.450.05 11 500-3 BN Flake 2.5 16.36 11.73 10.41 N 0.30 0.08 12 500-15 BNFlake 2.53 16.56 12.3 18.45 N 0.40 0.07 13 500-15 BN Flake 2.29 14.9611.79 20.96 N 0.45 0.07 14 Asbury 3268 3.35 21.90 12.38 12.38 N 0.280.05 15 Asbury 3268 3.35 21.90 12.38 12.38 N 0.28 0.05 16 Asbury 32682.83 18.49 10.43 9.25 N 0.25 0.06

Additional samples were made according to the following table. NoDISPERBYK 145 was included in these samples.

Sample No. Filler 1 Filler 2 TEPA qty (g) DER332 qty (g) Filler 1 qty(g) Filler 2 qty (g) Vol. Fraction Filler Vol. Fraction Magnetic FillerVol. Fraction non-flake Filler (e.g., bridging particles) 17 SendustHS80 500-15 BN Flake 1.66 10.84 10.5 15.75 0.53 0.07 0.13 TM1250 5.62AA18 5.62 18 Sendust HS80 500-15 BN Flake 1.99 13.01 11.2 16.8 0.48 0.070.08 TM1250 3.5 AA18 3.5 19 Sendust HS80 500-15 BN Flake 2.45 16.0510.08 15.12 0.40 0.06 0.06 TM1250 3.15 AA18 3.15 20 Sendust HS80 500-15BN Flake 2.26 14.74 11.88 17.82 0.45 0.07 0 500-3 BN Flake 3.3 21Sendust HS80 500-15 BN Flake 11.36 17.4 0.52 0.07 0 Platelets 012P200-15 BN Flake 2.25 2.25 500-3 BN Flake 2.25 22 BAK70 BAK10 4.14 27.170.31 23.44 0.48 0 0.48 23 BAK70 BAK10 1.33 8.67 69 23 0.78 0 0.78TM1250 23

After mixing, the coating solutions were cast into a sheet using a 12"(30.5 cm) wide notch bar with a 30 mil (0.76 mm) gap between twosilicone release liners (32N - 3 mil and 32N - 3 mil from SKC). Amagnetic field was then applied to the coated uncured composite samplesusing either a static magnet with a linear back and forth motion of thesample (denoted “Linear” in the table below) relative to the magnet, orusing a rotating magnet (denoted “Rotating” in the table below).

For the static magnet system, two aligned rare earth magnets wereseparated by 9.2 mm and the coated uncured composite was passed back andforth in the gap between the two magnets 30-60 times. It was found thatsimply holding the composite between the magnets was not enough to forcealignment/orientation in these systems. The measured field strength was4.37 kG between the two magnets. The magnets were of T550 type and ofrectangular dimensions (25 mm × 30 mm × 17 mm). They were obtained fromElectron Energy Corporation, Landisville, PA.

The rotating magnetic is described under “Assembly of Magnetic ApparatusII”. The coated uncured composite was passed back and forth for 20-30passes over the magnet over a period of ~1 min.

Coatings were then taped to a plastic board. The boards were placed inan oven at 70° C. for half an hour to cure the epoxy at which point theywere removed, and the liners were stripped off.

Thermal conductivities of the cured samples were measured using a LaserFlash Analysis (LFA) diffusivity method with an LFA 467 Hyper Flash(Netzsch). The test was run with a laser cut 12.7 mm disc that had beenspray coated in graphite to control emissivity. Data was collected witha sample temperature of 50° C., and three replicates were tested andaveraged for each coating. The LFA method provided a sample diffusivity.Several additional quantities were measured to determine the thermalconductivity: thickness was measured using a drop gauge, sample densitywas measured using an Archimedes' method (Mettler Toledo XSE204 w/density kit), and heat capacity was measured using a pyroceram referencematerial run at the same time as the samples.

Results are provided in the table below. “Aligned” samples are samplesthat were subjected to an applied magnetic field, while “unaligned”samples were not. The samples subjected to the rotating magnetic filesshowed that the Sendust particles tended to agglomerate into layers. Thesamples subjected to linear relative magnetic field motion showed atleast some degree of orientation of the Sendust particles in thethickness direction, but the particles were not agglomerated intolayers. FIG. 51 is an image of a cross-section of Sample 2. FIGS. 52 and52A are images of top and cross-sectional views, respectively, of Sample12. FIG. 53 is an image of a cross-section of a comparative version ofSample 21 which was unaligned. FIG. 53A is an image of a cross-sectionof Sample 21 which was aligned with the rotating magnet. The Sendustflakes appear as thin line segments in these images.

Sample No. Relative Field Motion Thermal Conductivity(Aligned/Unaligned) 1 Linear 3.2 W/mK Aligned 1.0 W/mK Unaligned 2Linear 4 W/mK Aligned 1.0 W/mK Unaligned 3 Linear 3.2 W/mK Aligned 1.0W/mK Unaligned 4 Linear 3.3 W/mK Aligned 1.1 W/mK Unaligned 5 Linear 1.6W/mK Aligned 6 Linear 4.3 W/mK Aligned 1.2 W/mK unaligned 7 Linear 2.8W/mK Aligned 0.8 W/mK unaligned 8 Linear 3.4 W/mK Aligned 9 Linear 3.2W/mK Aligned 1.2 W/mK unaligned 10 Linear Would not form into cohesivepaste to coat 11 Rotating 3.2 W/mK Aligned 12 Rotating 4.3 W/mK Aligned1.1 W/mK Unaligned 13 Rotating 4.5 W/mK Aligned 14 Linear 1.4 W/mKAligned 15 Rotating 2.4 W/mK Aligned 16 Rotating 3.3 W/mK Aligned 17Rotating 4.2 Aligned 18 Rotating 4.4 Aligned 19 Rotating 3.5 Aligned 20Rotating 4.9 Aligned 21 Rotating 5.2 Aligned 1.7 Unaligned 22 None 1.123 None 4.6

Example 10

Samples were made and tested as described for Example 9 except that thematerials in the following table were used in the coating solution. Inthe table, “aligned” samples are samples that were subjected to anapplied rotating magnetic field, while “unaligned” samples were notsubjected to an applied magnetic field. FIG. 54 is an image of across-section of a comparative version of Sample 1 that was notsubjected an applied magnetic field, and FIG. 54A is an image of across-section of Sample 1 which was subjected a rotating magnetic field.The Sendust flakes appear as thin line segments in these images whilethe boron nitride particles appear approximately circular.

Sample No. Filler 1 Filler 2 TEPA qty (g) DER332 qty (g) Filler 1(g)Filler 2 (g) Disp.? Total Filler Volume % Thermal Conductivity(Align/Unalign) W/mK 1 Sendust HS80 BAK90 1 6.5 2.98 23.8 N 63% 2.7Aligned BAK10 TM1250 7.87 7.87 2 Sendust HS80 BAK90 0.8 5.2 3.96 29.4 Y69% 3.1 Aligned BAK10 TM1250 5.5 5.5 3 Sendust HS80 BAK90 0.9 5.85 3.4627.68 N 66% 2.8 Aligned 2.3 Unaligned BAK10 TM1250 6.05 6.05 4 SendustHS80 BAK90 1.99 13.01 5.95 55.25 N 63% 2.6 Aligned 2.2 Unaligned BAK10TM1250 17 6.8 5 Sendust HS80 BAK90 1 6.5 3.83 27.63 N 63% 2.7 AlignedBAK10 TM1250 7.9 3.5 6 Sendust HS80 BAK90 0.8 5.2 3.96 29.04 Y 69% 3.2Aligned 2.3 Unaligned BAK10 TM1250 5.5 5.5 7 Sendust HS80 BAK90 1.338.67 3.15 54.41 Y 73% 4.3 Aligned 3.8 Unaligned BAK10 TM1250 20.93 8.378 Sendust HS80 BAK90 1.06 6.94 3.22 55.61 Y 78% 4.7 Aligned 4.5Unaligned BAK10 TM1250 21.39 8.56 9 Sendust HS80 BAK90 1.93 12.59 3.6262.52 N 63.6% 2.4 Aligned 2.2 Unaligned BAK10 TM1250 11.52 4.61 10Sendust HS80 BAK90 1.28 8.39 5.23 67.07 Y 73.3% 3.4 Aligned 3.2Unaligned BAK10 TM1250 10.58 4.23 11 Sendust HS80 BAK90 1.28 8.39 3.468.81 Y 73.3% 3.8 Aligned 3.6 Unaligned BAK10 TM1250 10.64 4.26 12Sendust HS80 BAK90 1.54 10.07 3.58 66.43 Y 69.3% 3.0 Aligned 2.9Unaligned BAK10 TM1250 10.83 4.33 13 Sendust HS80 BAK90 2.18 14.27 3.7862.66 N 60.0% 2.2 Aligned 1.9 Unaligned BAK10 TM1250 9.93 3.97 14Sendust HS80 BAK90 2.65 17.35 8 62.4 N 54.6% 1.9 Aligned 1.4 UnalignedBAK10 TM1250 6.86 2.74 15 Sendust HS80 BAK90 1.28 8.39 6.1 53.13 Y 73.3%3.8 Aligned 3.2 Unaligned BAK10 TM1250 13.94 13.94 16 Sendust HS80 BAK901.28 8.39 6.1 46.16 Y 73.3% 3.9 Aligned 3.3 Unaligned BAK10 TM1250 17.4217.42 17 Sendust HS80 BAK90 1.28 8.39 6.1 34.84 Y 73.3% 3.6 Aligned 3.2Unaligned BAK10 TM1250 23.08 23.08 18 Sendust HS80 BAK90 1.47 9.46 10.9143.79 Y 69.1% 3.2 Aligned 2.8 Unaligned BAK10 TM1250 14.6 14.6 19Sendust HS80 BAK90 1.24 8.07 8.57 46.27 Y 73.4% 3.9 Aligned 3.6Unaligned BAK10 TM1250 15.42 15.42 20 Sendust HS80 BAK90 2.45 15.9811.49 39.05 Y 54.9% 2.3 Aligned 1.7 Unaligned BAK10 TM1250 13.02 13.0221 Sendust HS80 BAK90 3.05 19.95 9.24 40.66 N 50% 2.3 Aligned 1.6Unaligned BAK10 TM1250 13.55 13.55 22 Sendust HS80 BAK90 4.11 26.89 8.2836.43 N 40% 1.5 Aligned 1.1 Unaligned BAK10 TM1250 12.14 12.14

For comparison, additional samples were made and tested as described forExample 9 except that the materials in the following table were used inthe coating solution, and no magnetic field was applied to the samples.No DISPERBYK 145 was included in these samples.

Sample No. Filler 1 Filler 2 TEPA qty (g) DER332 qty (g) Filler 1 qty(g) Filler 2 qty (g) Total Filler Volume % Thermal Conductivity (W/mK)23 BAK70 BAK10 2.49 16.26 79.69 26.56 64% 2.0 24 BAK70 BAK10 1.66 10.8484.38 28.13 74% 2.9 25 BAK70 BAK10 2.07 13.55 82.03 27.34 69% 2.5 26BAK70 BAK10 4.14 27.1 70.31 23.44 49% 1.1 27 BAK70 BAK10 1.33 8.67 69 2379% 4.6 TM1250 23 28 10.34 65.06 0% 0.2

FIG. 55 is a plot of thermal conductivity versus total filler volumeloading for various samples. FIG. 56 is a plot of the ratio of thethermal conductivity of aligned samples to the thermal conductivity ofcorresponding unaligned samples as a function of the ratio of volume ofmagnetic filler (Sendust) to total filler volume for various samples.

Terms such as “about” will be understood in the context in which theyare used and described in the present description by one of ordinaryskill in the art. If the use of “about” as applied to quantitiesexpressing feature sizes, amounts, and physical properties is nototherwise clear to one of ordinary skill in the art in the context inwhich it is used and described in the present description, “about” willbe understood to mean within 5 percent of the specified value. Aquantity given as about a specified value can be precisely the specifiedvalue. For example, if it is not otherwise clear to one of ordinaryskill in the art in the context in which it is used and described in thepresent description, a quantity having a value of about 1, means thatthe quantity has a value between 0.95 and 1.05, and that the value couldbe 1.

Descriptions for elements in figuresshould be understood to applyequally to corresponding elements in other figures, unless indicatedotherwise. Although specific embodiments have been illustrated anddescribed herein, it will be appreciated by those of ordinary skill inthe art that a variety of alternate and/or equivalent implementationscan be substituted for the specific embodiments shown and describedwithout departing from the scope of the present disclosure. Thisapplication is intended to cover any adaptations, or variations, orcombinations of the specific embodiments discussed herein. Therefore, itis intended that this disclosure be limited only by the claims and theequivalents thereof.

1-15. (canceled)
 16. An electrically conductive adhesive layercomprising a plurality of particles dispersed between opposing first andsecond major surfaces of the electrically conductive adhesive layerspaced apart a distance D, the particles agglomerated so as to form aplurality of substantially continuous layers of particles generallyextending along orthogonal first and second directions and arrangedalong a third direction, each substantially continuous layer ofparticles having a length L along the first direction from a first to anopposing second edge of the electrically conductive adhesive layer and awidth W along the second direction extending from the first to thesecond major surface, L/D ≥ 100, at least some of the particles beingelectrically conductive.
 17. The electrically conductive adhesive layerof claim 16, wherein each substantially continuous layer of particleshas a thickness T along a fourth direction orthogonal to the first andsecond directions, D/T ≥
 100. 18. The electrically conductive adhesivelayer of claim 17, wherein the third and fourth directions aresubstantially parallel.
 19. The electrically conductive adhesive layerof claim 16, wherein at least some of the substantially continuouslayers of particles are substantially parallel to one another.
 20. Theelectrically conductive adhesive layer of claim 16, wherein at least oneof the substantially continuous layers of particles splits at a forkinto first and second sublayers, each sublayer generally extending alongthe first and second directions.
 21. The electrically conductiveadhesive layer of claim 16, wherein W/D is in a range of about 1 to 1.5.22. A electrically conductive adhesive layer rolled along a length ofthe electrically conductive adhesive layer to form a roll, theelectrically conductive adhesive layer comprising a plurality ofsubstantially continuous layers of particles extending along the lengthand a thickness of the electrically conductive adhesive layer andarranged along a width of the electrically conductive adhesive layer,the electrically conductive adhesive layer having a substantially higherelectrical conductivity along each of the thickness and the length ofthe electrically conductive adhesive layer than the width of theelectrically conductive adhesive layer.
 23. The electrically conductiveadhesive layer of claim 22, wherein the plurality of substantiallycontinuous layers of particles comprises alternating first and secondsubstantially continuous layers of respective first and secondparticles, the first and second particles having different compositions,the second particles being electrically conductive.
 24. The electricallyconductive adhesive layer of claim 23, wherein the first and secondparticles have respective real parts of relative permeability µ'₁ andµ'₂, and wherein for at least one frequency less than about 1 GHz, µ'₁ /µ'₂ ≥
 5. 25. The electrically conductive adhesive layer of claim 22,wherein at least some of the substantially continuous layers ofparticles are substantially parallel to one another.
 26. Theelectrically conductive adhesive layer of claim 22, wherein theelectrical conductivity of the electrically conductive adhesive layeralong each of the thickness and the length of the electricallyconductive adhesive layer is at least a factor of 1.4 times theelectrical conductivity of the electrically conductive adhesive layeralong the width of the electrically conductive adhesive layer.
 27. Theelectrically conductive adhesive layer of claim 22, wherein theelectrical conductivity of the electrically conductive adhesive layeralong each of the thickness and the length of the electricallyconductive adhesive layer is at least a factor of 2 times the electricalconductivity of the electrically conductive adhesive layer along thewidth of the electrically conductive adhesive layer.
 28. Theelectrically conductive adhesive layer of claim 22, wherein theelectrical conductivity of the electrically conductive adhesive layeralong each of the thickness and the length of the electricallyconductive adhesive layer is at least a factor of 2.5 times theelectrical conductivity of the electrically conductive adhesive layeralong the width of the electrically conductive adhesive layer.
 29. Anelectrically conductive adhesive layer comprising a plurality ofalternating first and second substantially continuous layers ofrespective first and electrically conductive second particles, thealternating layers generally extending along orthogonal first and seconddirections and arranged along a third direction, the first and secondparticles having different compositions.
 30. The electrically conductiveadhesive layer of claim 29, wherein the first and second particles haverespective real parts of relative magnetic permeability µ'₁ and µ'₂, andwherein for at least one frequency less than about 1 GHz, µ'₁ / µ'₂ ≥ 5.31. The electrically conductive adhesive layer of claim 29, wherein atleast one of the first and second directions form an oblique angle withrespect to a thickness direction of the electrically conductive adhesivelayer.
 32. The electrically conductive adhesive layer of claim 29,wherein in each of at least a first layer cross-section of the layerorthogonal to the first direction and a second layer cross-section ofthe layer orthogonal to a thickness direction of the layer, an ellipsefitted to a cross-section of a two dimensional autocovariance of animage of the layer cross-section at 10% of a central peak of theautocovariance has a major axis length L1 and a minor axis length L2,L1/L2 ≥ 1.2.
 33. The electrically conductive adhesive layer of claim 29,wherein in at least a first layer cross-section of the layer orthogonalto the first direction and a second layer cross-section of the layerorthogonal to a thickness direction of the layer, a power spectraldensity of a positive portion of a two dimensional autocovariance of animage of the layer cross-section has a peak corresponding to a pitch ofless than about 100 micrometers.